Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights

Koop Lammertsma; Mark J.M. Vlaar

doi:10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x

Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights

Koop Lammertsma
, Mark J.M. Vlaar

Vrije Universiteit Amsterdam

Research output: Contribution to journal › Short survey › peer-review

210 Citations (Scopus)

Abstract

The versatile carbene-like chemistry of electrophilic phosphinidene complexes (R-P=ML_n) with C=C, C≡C, C=X, and C≡X (X = N, O, S, Si, and P) bonds and aromatics is discussed.

Original language	English
Pages (from-to)	1127-1138
Number of pages	12
Journal	European Journal of Organic Chemistry
Issue number	7
DOIs	https://doi.org/10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x
Publication status	Published - 2002
Externally published	Yes

Keywords

Carbenes
Phosphinidene complexes
Phosphorus heterocycles
Strained molecules

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

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10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x

Cite this

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title = "Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights",

abstract = "The versatile carbene-like chemistry of electrophilic phosphinidene complexes (R-P=MLn) with C=C, C≡C, C=X, and C≡X (X = N, O, S, Si, and P) bonds and aromatics is discussed.",

keywords = "Carbenes, Phosphinidene complexes, Phosphorus heterocycles, Strained molecules",

author = "Koop Lammertsma and Vlaar, \{Mark J.M.\}",

year = "2002",

doi = "10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x",

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pages = "1127--1138",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights

AU - Lammertsma, Koop

AU - Vlaar, Mark J.M.

PY - 2002

Y1 - 2002

N2 - The versatile carbene-like chemistry of electrophilic phosphinidene complexes (R-P=MLn) with C=C, C≡C, C=X, and C≡X (X = N, O, S, Si, and P) bonds and aromatics is discussed.

AB - The versatile carbene-like chemistry of electrophilic phosphinidene complexes (R-P=MLn) with C=C, C≡C, C=X, and C≡X (X = N, O, S, Si, and P) bonds and aromatics is discussed.

KW - Carbenes

KW - Phosphinidene complexes

KW - Phosphorus heterocycles

KW - Strained molecules

UR - https://www.scopus.com/pages/publications/0036206072

U2 - 10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x

DO - 10.1002/1099-0690(200204)2002:7<1127::aid-ejoc1127>3.0.co;2-x

M3 - Short survey

AN - SCOPUS:0036206072

SN - 1434-193X

SP - 1127

EP - 1138

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 7

ER -

Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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