Carbene-like chemistry of phosphinidene complexes - Reactions, applications, and mechanistic insights

Koop Lammertsma, Mark J.M. Vlaar

Research output: Contribution to journalShort surveypeer-review

207 Citations (Scopus)

Abstract

The versatile carbene-like chemistry of electrophilic phosphinidene complexes (R-P=MLn) with C=C, C≡C, C=X, and C≡X (X = N, O, S, Si, and P) bonds and aromatics is discussed.

Original languageEnglish
Pages (from-to)1127-1138
Number of pages12
JournalEuropean Journal of Organic Chemistry
Issue number7
DOIs
Publication statusPublished - 2002
Externally publishedYes

Keywords

  • Carbenes
  • Phosphinidene complexes
  • Phosphorus heterocycles
  • Strained molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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