Butane-1,4-diammonium bis(perchlorate)

Charmaine Arderne; Gert J. Kruger

doi:10.1107/S1600536811012025

Butane-1,4-diammonium bis(perchlorate)

Charmaine Arderne, Gert J. Kruger

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The butane-1,4-diammonium cation of the title compound, C₄H ₁₄N₂ ²⁺·2ClO₄ ^-, lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated interactions to the perchlorate anion. Complex hydrogenbonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R₁₀¹⁰(50) is identified.

Original language	English
Pages (from-to)	o1060
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	5
DOIs	https://doi.org/10.1107/S1600536811012025
Publication status	Published - May 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Butane-1,4-diammonium bis(perchlorate)",

abstract = "The butane-1,4-diammonium cation of the title compound, C4H 14N2 2+·2ClO4 -, lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated interactions to the perchlorate anion. Complex hydrogenbonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R1010(50) is identified.",

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N2 - The butane-1,4-diammonium cation of the title compound, C4H 14N2 2+·2ClO4 -, lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated interactions to the perchlorate anion. Complex hydrogenbonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R1010(50) is identified.

AB - The butane-1,4-diammonium cation of the title compound, C4H 14N2 2+·2ClO4 -, lies on a special position of site symmetry 2/m, whereas the perchlorate anion is located on a crystallographic mirror plane. An intricate three-dimensional hydrogen-bonding network exists in the crystal structure with each H atom of the ammonium group exhibiting bifurcated interactions to the perchlorate anion. Complex hydrogenbonded ring and chain motifs are also evident, in particular a 50-membered ring with graph-set notation R1010(50) is identified.

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ER -

Butane-1,4-diammonium bis(perchlorate)

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