Abstract
The synthesis, characterization and catalytic activity in ethylene polymerization of novel mononuclear vanadium complexes bearing N∧N∧N-tridentate (pyrazolyl-pyridine) ligands are described. With AlEtCl2 as co-catalyst, complexes 1 and 2 produce single-site catalysts that polymerized ethylene affording high density polyethylene with fairly narrow molecular weight distribution.
Original language | English |
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Pages (from-to) | 5327-5330 |
Number of pages | 4 |
Journal | Journal of Organometallic Chemistry |
Volume | 692 |
Issue number | 24 |
DOIs | |
Publication status | Published - 15 Nov 2007 |
Keywords
- Bis(pyrazolyl)pyridine
- Ethylene polymerization
- Polyethylene
- Vanadium(III) complexes
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry