Bis(dicyclohexylphenylphosphine)silver(I) nitrate

Andrew R. Burgoyne; Reinout Meijboom; Alfred Muller; Bernard Omondi

doi:10.1107/S1600536810011724

Bis(dicyclohexylphenylphosphine)silver(I) nitrate

Andrew R. Burgoyne, Reinout Meijboom, Alfred Muller, Bernard Omondi

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, [Ag(C₁₈H₂₇P)₂]NO ₃, is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counteranion, weakly interacting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) Å. The cationic silverphosphine complex has a nonlinear geometry in which the P - Ag - P angle is 154.662 (19)̊. The Ag - P bond lengths are 2.4303 (6) and 2.4046 (5) Å.

Original language	English
Pages (from-to)	m503-m504
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	5
DOIs	https://doi.org/10.1107/S1600536810011724
Publication status	Published - 14 Apr 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis(dicyclohexylphenylphosphine)silver(I) nitrate",

abstract = "The title compound, [Ag(C18H27P)2]NO 3, is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counteranion, weakly interacting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) {\AA}. The cationic silverphosphine complex has a nonlinear geometry in which the P - Ag - P angle is 154.662 (19)̊. The Ag - P bond lengths are 2.4303 (6) and 2.4046 (5) {\AA}.",

author = "Burgoyne, {Andrew R.} and Reinout Meijboom and Alfred Muller and Bernard Omondi",

year = "2010",

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day = "14",

doi = "10.1107/S1600536810011724",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - Bis(dicyclohexylphenylphosphine)silver(I) nitrate

AU - Burgoyne, Andrew R.

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Omondi, Bernard

PY - 2010/4/14

Y1 - 2010/4/14

N2 - The title compound, [Ag(C18H27P)2]NO 3, is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counteranion, weakly interacting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) Å. The cationic silverphosphine complex has a nonlinear geometry in which the P - Ag - P angle is 154.662 (19)̊. The Ag - P bond lengths are 2.4303 (6) and 2.4046 (5) Å.

AB - The title compound, [Ag(C18H27P)2]NO 3, is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counteranion, weakly interacting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) Å. The cationic silverphosphine complex has a nonlinear geometry in which the P - Ag - P angle is 154.662 (19)̊. The Ag - P bond lengths are 2.4303 (6) and 2.4046 (5) Å.

UR - http://www.scopus.com/inward/record.url?scp=77952036032&partnerID=8YFLogxK

U2 - 10.1107/S1600536810011724

DO - 10.1107/S1600536810011724

M3 - Article

AN - SCOPUS:77952036032

SN - 1600-5368

VL - 66

SP - m503-m504

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Bis(dicyclohexylphenylphosphine)silver(I) nitrate

Abstract

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