Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate

Apollinaire Munyaneza, Reinout Meijboom, Bernard Omondi

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)


In the title compound, [Ag{P(C6H11) 2(C6H5)}2]ClO4· CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag - P = 2.3993 (4) and 2.4011 (4) Å; P - Ag - P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯Operchlorate inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C - H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

Original languageEnglish
Pages (from-to)m483-m484
JournalActa Crystallographica Section E: Structure Reports Online
Issue number4
Publication statusPublished - Apr 2011

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


Dive into the research topics of 'Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate'. Together they form a unique fingerprint.

Cite this