Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate

Apollinaire Munyaneza; Reinout Meijboom; Bernard Omondi

doi:10.1107/S1600536811009822

Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate

Apollinaire Munyaneza, Reinout Meijboom, Bernard Omondi

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [Ag{P(C₆H₁₁) ₂(C₆H₅)}₂]ClO₄· CH₂Cl₂, the Ag^I atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag - P = 2.3993 (4) and 2.4011 (4) Å; P - Ag - P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O_perchlorate inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag^I atom. Weak intermolecular C - H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

Original language	English
Pages (from-to)	m483-m484
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	4
DOIs	https://doi.org/10.1107/S1600536811009822
Publication status	Published - Apr 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate",

abstract = "In the title compound, [Ag{P(C6H11) 2(C6H5)}2]ClO4· CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag - P = 2.3993 (4) and 2.4011 (4) {\AA}; P - Ag - P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯Operchlorate inter-action of 2.873 (2) {\AA}, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C - H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.",

author = "Apollinaire Munyaneza and Reinout Meijboom and Bernard Omondi",

year = "2011",

month = apr,

doi = "10.1107/S1600536811009822",

language = "English",

volume = "67",

pages = "m483--m484",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

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TY - JOUR

T1 - Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate

AU - Munyaneza, Apollinaire

AU - Meijboom, Reinout

AU - Omondi, Bernard

PY - 2011/4

Y1 - 2011/4

N2 - In the title compound, [Ag{P(C6H11) 2(C6H5)}2]ClO4· CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag - P = 2.3993 (4) and 2.4011 (4) Å; P - Ag - P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯Operchlorate inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C - H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

AB - In the title compound, [Ag{P(C6H11) 2(C6H5)}2]ClO4· CH2Cl2, the AgI atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag - P = 2.3993 (4) and 2.4011 (4) Å; P - Ag - P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯Operchlorate inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the AgI atom. Weak intermolecular C - H⋯O hydrogen-bonding interactions involving phenyl, cyclohexyl and dichloromethane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

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U2 - 10.1107/S1600536811009822

DO - 10.1107/S1600536811009822

M3 - Article

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VL - 67

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Bis[dicyclohexyl(phenyl)phosphane-KP]silver(I) perchlorate dichloromethane monosolvate

Abstract

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