Bis(acetonitrile-N)dichlorido( 4-cyclo-octa-1,5-diene) ruthenium(II) acetonitrile monosolvate

Haleden Chiririwa; Reinout Meijboom; Samson O. Owalude; Uche B. Eke; Charmaine Arderne

doi:10.1107/S1600536811027723

Bis(acetonitrile-N)dichlorido( ⁴-cyclo-octa-1,5-diene) ruthenium(II) acetonitrile monosolvate

Haleden Chiririwa
, Reinout Meijboom
, Samson O. Owalude
, Uche B. Eke
, Charmaine Arderne

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the title Ru ^II complex, [RuCl ₂(C ₈H ₁₂)(C ₂H ₃N) ₂]·CH ₃CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN molecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru ^II atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent molecule per molecule which is outside the coordination sphere of the ruthenium atom.

Original language	English
Pages (from-to)	m1096
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	8
DOIs	https://doi.org/10.1107/S1600536811027723
Publication status	Published - Aug 2011

Keywords

R factor = 0.022
T = 100 K
data-to-parameter ratio = 22.4
mean σ(CC) = 0.003 Å
single-crystal X-ray study
wR factor = 0.054

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811027723

Cite this

@article{89de075a01a54b36b9a8a2c61119efcc,

title = "Bis(acetonitrile-N)dichlorido( 4-cyclo-octa-1,5-diene) ruthenium(II) acetonitrile monosolvate",

abstract = "In the title Ru II complex, [RuCl 2(C 8H 12)(C 2H 3N) 2]·CH 3CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN molecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru II atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent molecule per molecule which is outside the coordination sphere of the ruthenium atom.",

keywords = "R factor = 0.022, T = 100 K, data-to-parameter ratio = 22.4, mean σ(CC) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.054",

author = "Haleden Chiririwa and Reinout Meijboom and Owalude, \{Samson O.\} and Eke, \{Uche B.\} and Charmaine Arderne",

year = "2011",

month = aug,

doi = "10.1107/S1600536811027723",

language = "English",

volume = "67",

pages = "m1096",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - Bis(acetonitrile-N)dichlorido( 4-cyclo-octa-1,5-diene) ruthenium(II) acetonitrile monosolvate

AU - Chiririwa, Haleden

AU - Meijboom, Reinout

AU - Owalude, Samson O.

AU - Eke, Uche B.

AU - Arderne, Charmaine

PY - 2011/8

Y1 - 2011/8

N2 - In the title Ru II complex, [RuCl 2(C 8H 12)(C 2H 3N) 2]·CH 3CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN molecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru II atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent molecule per molecule which is outside the coordination sphere of the ruthenium atom.

AB - In the title Ru II complex, [RuCl 2(C 8H 12)(C 2H 3N) 2]·CH 3CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN molecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru II atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent molecule per molecule which is outside the coordination sphere of the ruthenium atom.

KW - R factor = 0.022

KW - T = 100 K

KW - data-to-parameter ratio = 22.4

KW - mean σ(CC) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.054

UR - https://www.scopus.com/pages/publications/80051540481

U2 - 10.1107/S1600536811027723

DO - 10.1107/S1600536811027723

M3 - Article

AN - SCOPUS:80051540481

SN - 1600-5368

VL - 67

SP - m1096

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -