Bis[(4-methylphenyl)diphenylphosphine-κP](nitrito-κ2O,O′)silver(I)

Kariska Potgieter; Frederick P. Malan; Oyekunle Azeez Alimi; Reinout Meijboom; E. R.T. Tiekink

doi:10.1107/S2414314622007714

Bis[(4-methylphenyl)diphenylphosphine-κP](nitrito-κ²O,O′)silver(I)

Kariska Potgieter, Frederick P. Malan, Oyekunle Azeez Alimi, Reinout Meijboom, E. R.T. Tiekink

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The title AgI complex, [Ag(NO2)(C19H17P)2], reveals a distorted pseudo-trigonal-planar shape around the AgI atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O - Ag - O angle of 51.44 (9)°. The plane resulting from the NO2 coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°].

Original language	English
Article number	x220771
Journal	IUCrData
Volume	7
Issue number	Pt 8
DOIs	https://doi.org/10.1107/S2414314622007714
Publication status	Published - 1 Aug 2022

Keywords

crystal structure
diphenyl-p-tolylphosphine
nitrite
silver(I) complex

ASJC Scopus subject areas

Analytical Chemistry
Inorganic Chemistry
Organic Chemistry

Access to Document

10.1107/S2414314622007714

Cite this

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title = "Bis[(4-methylphenyl)diphenylphosphine-κP](nitrito-κ2O,O′)silver(I)",

abstract = "The title AgI complex, [Ag(NO2)(C19H17P)2], reveals a distorted pseudo-trigonal-planar shape around the AgI atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O - Ag - O angle of 51.44 (9)°. The plane resulting from the NO2 coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°].",

keywords = "crystal structure, diphenyl-p-tolylphosphine, nitrite, silver(I) complex",

author = "Kariska Potgieter and Malan, {Frederick P.} and Alimi, {Oyekunle Azeez} and Reinout Meijboom and Tiekink, {E. R.T.}",

note = "Publisher Copyright: {\textcopyright} 2022 Potgieter et al.",

year = "2022",

month = aug,

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doi = "10.1107/S2414314622007714",

language = "English",

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TY - JOUR

T1 - Bis[(4-methylphenyl)diphenylphosphine-κP](nitrito-κ2O,O′)silver(I)

AU - Potgieter, Kariska

AU - Malan, Frederick P.

AU - Alimi, Oyekunle Azeez

AU - Meijboom, Reinout

AU - Tiekink, E. R.T.

PY - 2022/8/1

Y1 - 2022/8/1

N2 - The title AgI complex, [Ag(NO2)(C19H17P)2], reveals a distorted pseudo-trigonal-planar shape around the AgI atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O - Ag - O angle of 51.44 (9)°. The plane resulting from the NO2 coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°].

AB - The title AgI complex, [Ag(NO2)(C19H17P)2], reveals a distorted pseudo-trigonal-planar shape around the AgI atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O - Ag - O angle of 51.44 (9)°. The plane resulting from the NO2 coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°].

KW - crystal structure

KW - diphenyl-p-tolylphosphine

KW - nitrite

KW - silver(I) complex

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