Bis[(4-methyl­phen­yl)di­phenyl­phosphane-κP](nitrato-κ2O,O′)silver(I)

Frederick P. Malan; Kariska Potgieter; Reinout Meijboom

doi:10.1107/S2414314622010458

Bis[(4-methylphenyl)diphenylphosphane-κP](nitrato-κ²O,O′)silver(I)

Frederick P. Malan, Kariska Potgieter, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The molecular structure of the title AgI complex, [Ag(NO3)(C19H17P)2] or [Ag{(p-CH3C6H4)(C6H5)2P-κP}2-NO3-κ2 O:O′], is described, where a distorted trigonal-planar coordination environment is exhibited about the central AgI atom; in this description, the two O atoms are assumed to occupy one position in the coordination sphere. The compound crystallized with half a molecule in the asymmetric unit having the AgI atom lying on a twofold axis.

Original language	English
Article number	x221045
Journal	IUCrData
Volume	7
DOIs	https://doi.org/10.1107/S2414314622010458
Publication status	Published - 8 Nov 2022

Keywords

crystal structure
diphenyl-p-Tolyl phosphine
nitrate
silver(I) complex

ASJC Scopus subject areas

Analytical Chemistry
Inorganic Chemistry
Organic Chemistry

Access to Document

10.1107/S2414314622010458

Cite this

@article{b4217460d761404c8f8ae22f2130020f,

title = "Bis[(4-methylphenyl)diphenylphosphane-κP](nitrato-κ2O,O′)silver(I)",

abstract = "The molecular structure of the title AgI complex, [Ag(NO3)(C19H17P)2] or [Ag{(p-CH3C6H4)(C6H5)2P-κP}2-NO3-κ2 O:O′], is described, where a distorted trigonal-planar coordination environment is exhibited about the central AgI atom; in this description, the two O atoms are assumed to occupy one position in the coordination sphere. The compound crystallized with half a molecule in the asymmetric unit having the AgI atom lying on a twofold axis.",

keywords = "crystal structure, diphenyl-p-Tolyl phosphine, nitrate, silver(I) complex",

author = "Malan, {Frederick P.} and Kariska Potgieter and Reinout Meijboom",

year = "2022",

month = nov,

day = "8",

doi = "10.1107/S2414314622010458",

language = "English",

volume = "7",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Bis[(4-methylphenyl)diphenylphosphane-κP](nitrato-κ2O,O′)silver(I)

AU - Malan, Frederick P.

AU - Potgieter, Kariska

AU - Meijboom, Reinout

PY - 2022/11/8

Y1 - 2022/11/8

N2 - The molecular structure of the title AgI complex, [Ag(NO3)(C19H17P)2] or [Ag{(p-CH3C6H4)(C6H5)2P-κP}2-NO3-κ2 O:O′], is described, where a distorted trigonal-planar coordination environment is exhibited about the central AgI atom; in this description, the two O atoms are assumed to occupy one position in the coordination sphere. The compound crystallized with half a molecule in the asymmetric unit having the AgI atom lying on a twofold axis.

AB - The molecular structure of the title AgI complex, [Ag(NO3)(C19H17P)2] or [Ag{(p-CH3C6H4)(C6H5)2P-κP}2-NO3-κ2 O:O′], is described, where a distorted trigonal-planar coordination environment is exhibited about the central AgI atom; in this description, the two O atoms are assumed to occupy one position in the coordination sphere. The compound crystallized with half a molecule in the asymmetric unit having the AgI atom lying on a twofold axis.

KW - crystal structure

KW - diphenyl-p-Tolyl phosphine

KW - nitrate

KW - silver(I) complex

UR - http://www.scopus.com/inward/record.url?scp=85149387588&partnerID=8YFLogxK

U2 - 10.1107/S2414314622010458

DO - 10.1107/S2414314622010458

M3 - Article

AN - SCOPUS:85149387588

SN - 2414-3146

VL - 7

JO - IUCrData

JF - IUCrData

M1 - x221045

ER -

Bis[(4-methylphenyl)diphenylphosphane-κP](nitrato-κ²O,O′)silver(I)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this

Bis[(4-methyl­phen­yl)di­phenyl­phosphane-κP](nitrato-κ2O,O′)silver(I)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this

Bis[(4-methylphenyl)diphenylphosphane-κP](nitrato-κ²O,O′)silver(I)