Bis[(2-methyl)diphosphane-κP](nitrito-κ2O,O′)silver(I)

Frederick P. Malan; Kariska Potgieter; Reinout Meijboom

doi:10.1107/S2414314625001932

Bis[(2-methyl)diphosphane-κP](nitrito-κ²O,O′)silver(I)

Frederick P. Malan, Kariska Potgieter, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P-Ag-P [129.126 (16)°] is noted. The O-Ag-O chelate angle is = 50.38 (6)° and the P-Ag-O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C-H⋯O interactions are evident.

Original language	English
Journal	IUCrData
Volume	10
Issue number	Pt 3
DOIs	https://doi.org/10.1107/S2414314625001932
Publication status	Published - 1 Mar 2025

Keywords

crystal structure
diphenyl-2-methoxyphenyl phosphine
nitrite
silver(I) complex

ASJC Scopus subject areas

Analytical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1107/S2414314625001932

Cite this

@article{c34706029aa54712a98b1caab6ea93c3,

title = "Bis[(2-methyl)diphosphane-κP](nitrito-κ2O,O′)silver(I)",

abstract = "The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P-Ag-P [129.126 (16)°] is noted. The O-Ag-O chelate angle is = 50.38 (6)° and the P-Ag-O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C-H⋯O interactions are evident.",

keywords = "crystal structure, diphenyl-2-methoxyphenyl phosphine, nitrite, silver(I) complex",

author = "Malan, {Frederick P.} and Kariska Potgieter and Reinout Meijboom",

year = "2025",

month = mar,

day = "1",

doi = "10.1107/S2414314625001932",

language = "English",

volume = "10",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

number = "Pt 3",

}

TY - JOUR

T1 - Bis[(2-methyl)diphosphane-κP](nitrito-κ2O,O′)silver(I)

AU - Malan, Frederick P.

AU - Potgieter, Kariska

AU - Meijboom, Reinout

PY - 2025/3/1

Y1 - 2025/3/1

N2 - The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P-Ag-P [129.126 (16)°] is noted. The O-Ag-O chelate angle is = 50.38 (6)° and the P-Ag-O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C-H⋯O interactions are evident.

AB - The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P-Ag-P [129.126 (16)°] is noted. The O-Ag-O chelate angle is = 50.38 (6)° and the P-Ag-O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C-H⋯O interactions are evident.

KW - crystal structure

KW - diphenyl-2-methoxyphenyl phosphine

KW - nitrite

KW - silver(I) complex

UR - http://www.scopus.com/inward/record.url?scp=105003469877&partnerID=8YFLogxK

U2 - 10.1107/S2414314625001932

DO - 10.1107/S2414314625001932

M3 - Article

AN - SCOPUS:105003469877

SN - 2414-3146

VL - 10

JO - IUCrData

JF - IUCrData

IS - Pt 3

ER -