{Bis[2-(3,5-dimethylpyrazol-1-yl-κN 2)ethyl]amine- κN}chloridopalladium(II) chloride 0.25-hydrate

Ilia A. Guzei; Lara C. Spencer; Nangamso Miti; James Darkwa

doi:10.1107/S1600536810035427

{Bis[2-(3,5-dimethylpyrazol-1-yl-κN ²)ethyl]amine- κN}chloridopalladium(II) chloride 0.25-hydrate

Ilia A. Guzei, Lara C. Spencer, Nangamso Miti, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, [PdCl(C₁₄H₂₃N₅)] Cl·0.25H₂O, is a pseudopolymorph of the previously reported compound [PdCl(C₁₄H₂₃N₅)]Cl·2H ₂O [de Mendoza et al. (2006). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.

Original language	English
Pages (from-to)	m1243
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S1600536810035427
Publication status	Published - Oct 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "{Bis[2-(3,5-dimethylpyrazol-1-yl-κN 2)ethyl]amine- κN}chloridopalladium(II) chloride 0.25-hydrate",

abstract = "The title compound, [PdCl(C14H23N5)] Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H 2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.",

author = "Guzei, {Ilia A.} and Spencer, {Lara C.} and Nangamso Miti and James Darkwa",

year = "2010",

month = oct,

doi = "10.1107/S1600536810035427",

language = "English",

volume = "66",

pages = "m1243",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "10",

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TY - JOUR

T1 - {Bis[2-(3,5-dimethylpyrazol-1-yl-κN 2)ethyl]amine- κN}chloridopalladium(II) chloride 0.25-hydrate

AU - Guzei, Ilia A.

AU - Spencer, Lara C.

AU - Miti, Nangamso

AU - Darkwa, James

PY - 2010/10

Y1 - 2010/10

N2 - The title compound, [PdCl(C14H23N5)] Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H 2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.

AB - The title compound, [PdCl(C14H23N5)] Cl·0.25H2O, is a pseudopolymorph of the previously reported compound [PdCl(C14H23N5)]Cl·2H 2O [de Mendoza et al. (2006). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.

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U2 - 10.1107/S1600536810035427

DO - 10.1107/S1600536810035427

M3 - Article

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SN - 1600-5368

VL - 66

SP - m1243

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

{Bis[2-(3,5-dimethylpyrazol-1-yl-κN ²)ethyl]amine- κN}chloridopalladium(II) chloride 0.25-hydrate

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