Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butyl-phosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]

Charmaine Arderne; Cedric W. Holzapfel

doi:10.1107/S1600536812037786

Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butyl-phosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]

Charmaine Arderne, Cedric W. Holzapfel

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, (C₂₀H₂₆P)₂[Pd ₂Cl₆], the Pd^II atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation. Only weak C-H···π interactions are present in the crystal structure.

Original language	English
Pages (from-to)	m1247
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	10
DOIs	https://doi.org/10.1107/S1600536812037786
Publication status	Published - Oct 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butyl-phosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]",

abstract = "In the title compound, (C20H26P)2[Pd 2Cl6], the PdII atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation. Only weak C-H···π interactions are present in the crystal structure.",

author = "Charmaine Arderne and Holzapfel, {Cedric W.}",

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T1 - Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butyl-phosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]

AU - Arderne, Charmaine

AU - Holzapfel, Cedric W.

PY - 2012/10

Y1 - 2012/10

N2 - In the title compound, (C20H26P)2[Pd 2Cl6], the PdII atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation. Only weak C-H···π interactions are present in the crystal structure.

AB - In the title compound, (C20H26P)2[Pd 2Cl6], the PdII atom within the hexachloridodipalladate(II) dianion has a square-planar geometry. It resides on a centre of inversion with the asymmetric unit containing half of the dianion and one phosphonium cation. Only weak C-H···π interactions are present in the crystal structure.

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DO - 10.1107/S1600536812037786

M3 - Article

AN - SCOPUS:84867200090

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VL - 68

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

Bis[(1,1′-biphenyl-2,2′-diyl)di-tert-butyl-phosphonium] di-μ-chlorido-bis[dichloridopalladate(II)]

Abstract

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