Abstract
The mass transfer efficiency and structural stability of the electrode are critical for industrialized water electrolysis operations. Herein, the biomimicry-inspired design of Ni3N/FeNi3N/NF nanoarrays with a fish scale-like structure, which endowed the Ni3N/FeNi3N/NF nanoarrays with rapid infiltration of aqueous solution within 60 ms and 169° bubble contact angle, is demonstrated. The optimal Ni3N/FeNi3N/NF sample displayed catalytic activity with hydrogen evolution reaction (HER) overpotentials of only 48 mV at 10 mA cm−2 and 102 mV at 100 mA cm−2. Similarly, the overpotential of the anodic-coupled urea oxidation reaction (UOR) was only 1.3 V at 10 mA cm−2 and 1.35 V at 100 mA cm−2. Besides, the small impact resulting from the rapid bubble extraction within the Ni3N/FeNi3N/NF nanoarrays ensured excellent HER cycling stability over 100 h at a current density of 50 mA cm−2. The further scale-up experiment suggests the industrialization prospects of the prepared Ni3N/FeNi3N/NF electrocatalysts.
Original language | English |
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Pages (from-to) | 1813-1823 |
Number of pages | 11 |
Journal | Nanoscale |
Volume | 15 |
Issue number | 4 |
DOIs | |
Publication status | Published - 19 Dec 2022 |
ASJC Scopus subject areas
- General Materials Science