TY - JOUR
T1 - Augmentation of Neodymium Ions Removal from Water Using Two Lanthanides-Based MOF
T2 - Ameliorated Efficiency by Synergistic Interaction of Two Lanthanides
AU - Najafi, Mahsa
AU - Sadeghi Chevinli, Ahmad
AU - Srivastava, Varsha
AU - Sillanpää, Mika
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/6/5
Y1 - 2019/6/5
N2 - To overcome the shortage of freshwater resources and provide clean water for worldwide population, along with the elimination or reduction of water contamination, we have synthesized the mixed-lanthanide metal-organic framework (MOF) with the formula m(x)M(1-x)BTC(DMF) {m = Ce(III), M = La(III), x = 0.8} via the solvothermal technique to separate Nd ions from water. The cooperative interaction between La(III) and Ce(III) has intensified the nonlinear properties of Ce0.8La0.2BTC(DMF) resulting in the high interaction between fabricated MOF and Nd ions. The as-prepared MOF was considered for various structural analyses and experimental conditions. Significantly, over 80% of Nd ions have been removed within 5 min and the maximum Nd uptake capacity (qmax) determined by the Langmuir isotherm was 142.8 mg/g.
AB - To overcome the shortage of freshwater resources and provide clean water for worldwide population, along with the elimination or reduction of water contamination, we have synthesized the mixed-lanthanide metal-organic framework (MOF) with the formula m(x)M(1-x)BTC(DMF) {m = Ce(III), M = La(III), x = 0.8} via the solvothermal technique to separate Nd ions from water. The cooperative interaction between La(III) and Ce(III) has intensified the nonlinear properties of Ce0.8La0.2BTC(DMF) resulting in the high interaction between fabricated MOF and Nd ions. The as-prepared MOF was considered for various structural analyses and experimental conditions. Significantly, over 80% of Nd ions have been removed within 5 min and the maximum Nd uptake capacity (qmax) determined by the Langmuir isotherm was 142.8 mg/g.
UR - http://www.scopus.com/inward/record.url?scp=85069751395&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.9b00207
DO - 10.1021/acs.jced.9b00207
M3 - Article
AN - SCOPUS:85069751395
SN - 0021-9568
VL - 64
SP - 3105
EP - 3112
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
IS - 7
ER -