TY - JOUR
T1 - Application of mullite-zeolite-alumina microfiltration membranes coated by SiO2 nanoparticles for separation of oil-in-water emulsions
AU - Jafari, Behrouz
AU - Rezaei, Edris
AU - Abbasi, Mohsen
AU - Hashemifard, Seyed Abdollatif
AU - khosravi, Arash
AU - Sillanpää, Mika
N1 - Publisher Copyright:
© 2022
PY - 2022/10
Y1 - 2022/10
N2 - The main objective of this work is the manipulation of hydrophilic materials in support, intermediate and selective layer to synthesize a novel nano-tubular ceramic membrane for treatment of oily wastewater. First, porous mullite-alumina-zeolite composite membranes were prepared by an extrusion method. Changes in porosity, pore size, shrinkage, and mechanical strength of the support membranes were investigated as function of percentage composition and sintering temperature in order to obtain the optimal conditions. According to the results, the most favorable condition set was determined to be a support membrane with a weight percent of 50, 30, and 20 for mullite, alumina, and zeolite, respectively, and a porosity of 38%, a pore size of 0.39 µm, and a shrinkage of 10.2% sintered at 1250 °C and with good mechanical properties at 24.6 MPa. The cross-flow filtration technique was employed to coat the natural zeolite on the inner surface of the support membrane to achieve a narrower pore size distribution. Finally, a thick layer of nano-SiO2 was coated on the membrane by utilizing the dip-coating method to develop a hydrophilic membrane while avoiding defects. Moreover, scanning electron microscopic (SEM) analysis of the SiO2 membranes showed that the natural zeolite and nano-SiO2 layer is homogeneous and demonstrates high adhesion to the support membrane. Besides, the result of COD rejection showed that the SiO2 membranes have an undeniable capability in rejection of oil droplets with a reasonable permeation flux. Therefore, the obtained membranes are highly promising for practical applications and environmental remediation in sensitive Persian Gulf zone.
AB - The main objective of this work is the manipulation of hydrophilic materials in support, intermediate and selective layer to synthesize a novel nano-tubular ceramic membrane for treatment of oily wastewater. First, porous mullite-alumina-zeolite composite membranes were prepared by an extrusion method. Changes in porosity, pore size, shrinkage, and mechanical strength of the support membranes were investigated as function of percentage composition and sintering temperature in order to obtain the optimal conditions. According to the results, the most favorable condition set was determined to be a support membrane with a weight percent of 50, 30, and 20 for mullite, alumina, and zeolite, respectively, and a porosity of 38%, a pore size of 0.39 µm, and a shrinkage of 10.2% sintered at 1250 °C and with good mechanical properties at 24.6 MPa. The cross-flow filtration technique was employed to coat the natural zeolite on the inner surface of the support membrane to achieve a narrower pore size distribution. Finally, a thick layer of nano-SiO2 was coated on the membrane by utilizing the dip-coating method to develop a hydrophilic membrane while avoiding defects. Moreover, scanning electron microscopic (SEM) analysis of the SiO2 membranes showed that the natural zeolite and nano-SiO2 layer is homogeneous and demonstrates high adhesion to the support membrane. Besides, the result of COD rejection showed that the SiO2 membranes have an undeniable capability in rejection of oil droplets with a reasonable permeation flux. Therefore, the obtained membranes are highly promising for practical applications and environmental remediation in sensitive Persian Gulf zone.
KW - Mullite-alumina-zeolite
KW - Nano-SiO
KW - Oil-water separation
KW - Support ceramic membrane
UR - http://www.scopus.com/inward/record.url?scp=85133741979&partnerID=8YFLogxK
U2 - 10.1016/j.jeurceramsoc.2022.06.060
DO - 10.1016/j.jeurceramsoc.2022.06.060
M3 - Article
AN - SCOPUS:85133741979
SN - 0955-2219
VL - 42
SP - 6005
EP - 6014
JO - Journal of the European Ceramic Society
JF - Journal of the European Ceramic Society
IS - 13
ER -