Anisotropic magnetic properties oC single crystals

Magnetic and transport properties of single crystals of (Formula presented)(Formula presented)C have been investigated by ac susceptibility, dc magnetization, specific heat, and resistance measurements. The compound shows highly anisotropic magnetic properties which come about as a result of the Tb magnetic moments lying predominantly in the ab plane. The ac susceptibility and low-field dc magnetization measurements indicate the presence of two magnetic transitions; one due to the antiferromagnetic (AFM) ordering of the Tb moments around 15 K, and another at 5 K, which we believe is due to a spin reorientation of the Tb moments. The resistivity ((Formula presented)) measurements show a sharp decrease in the resistance at 15 K but contain no observable features corresponding to the lower-temperature transition. The compound does not show superconductivity above 300 mK. Specific heat at low temperatures shows a large λ-type anomaly at 13.8 K in addition to the anomalies associated with the AFM ordering of the Tb moments at 15 K ((Formula presented)) and the spin reorientation at 5 K. Magnetization (M) and (Formula presented)(T) measurements indicate a decrease in (Formula presented) as a function of applied field (H) for H∥ab, whereas for H∥c, (Formula presented) is independent of field. The M-H isotherms at 2 K show that for H∥ab the compound goes through a series of temperature-dependent metamagnetic states before finally saturating into a ferromagnetic state for H≳21 kOe. For H∥c the compound shows a linear M-H behavior expected for a normal AFM compound. The (Formula presented)(H) measurements show anomalies due to the metamagnetic transitions and a large negative magnetoresistance above 21 kOe for H∥ab.