Adsorptive and photocatalytic remediation of hazardous organic chemical pollutants in aqueous medium: A review

The provision of clean water is still a major challenge in developing parts of the world, as emphasized by the United Nation Sustainable Development Goals (SDG 6), and has remained a subject of extensive research globally. Advancements in science and industry have resulted in a massive surge in the amount of industrial chemicals produced within the last few decades. Persistent and emerging organic pollutants are detected in aquatic environments, and conventional wastewater treatment plants have ineffectively handled these trace, bioaccumulative and toxic compounds. Therefore, we have conducted an extensive bibliometric analysis of different materials utilized to combat organic pollutants via adsorption and photocatalysis. The classes of pollutants, material synthesis, mechanisms of interaction, merits, and challenges were comprehensively discussed. The paper highlights the advantages of various materials used in the removal of hazardous pollutants from wastewater with activated carbon having the highest adsorption capacity. Dyes, pharmaceuticals, endocrine-disrupting chemicals, pesticides and other recalcitrant organic pollutants have been successfully removed at high degradation efficiencies through the photocatalytic process. The photocatalytic degradation and adsorption processes were compared by considering factors such as cost, efficiency, ease of application and reusability. This review will be good resource material for water treatment professionals/scientists, who may be interested in adsorptive and photocatalytic remediation of organic chemicals pollutants.