(Acetylacetonato-κ 2 O,O′)carbon-yl[tris-(naphthalen- 1-yl)phosphane-κP]rhodium(I) acetone hemisolvate

Hezron Ogutu; Reinout Meijboom

doi:10.1107/S1600536812008148

(Acetylacetonato-κ ² O,O′)carbon-yl[tris-(naphthalen- 1-yl)phosphane-κP]rhodium(I) acetone hemisolvate

Hezron Ogutu, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The title compound, [Rh(C ₅H ₇O ₂)(C ₃₀H ₂₁P)(CO)]·0.5C ₃H ₆O, has two different complex molecules in the asymmetric unit, with the Rh ^I atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.

Original language	English
Pages (from-to)	m394
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	4
DOIs	https://doi.org/10.1107/S1600536812008148
Publication status	Published - Apr 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(Acetylacetonato-κ 2 O,O′)carbon-yl[tris-(naphthalen- 1-yl)phosphane-κP]rhodium(I) acetone hemisolvate",

abstract = "The title compound, [Rh(C 5H 7O 2)(C 30H 21P)(CO)]·0.5C 3H 6O, has two different complex molecules in the asymmetric unit, with the Rh I atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.",

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year = "2012",

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AU - Meijboom, Reinout

PY - 2012/4

Y1 - 2012/4

N2 - The title compound, [Rh(C 5H 7O 2)(C 30H 21P)(CO)]·0.5C 3H 6O, has two different complex molecules in the asymmetric unit, with the Rh I atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.

AB - The title compound, [Rh(C 5H 7O 2)(C 30H 21P)(CO)]·0.5C 3H 6O, has two different complex molecules in the asymmetric unit, with the Rh I atoms in slightly distorted square-planar coordination environments. The molecules are packed as two monomeric mol-ecules with one acetone solvent mol-ecule sitting at the centre.

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JO - Acta Crystallographica Section E: Structure Reports Online

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(Acetylacetonato-κ ² O,O′)carbon-yl[tris-(naphthalen- 1-yl)phosphane-κP]rhodium(I) acetone hemisolvate

Abstract

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