(Acetyl-acetonato-κ2 O,O′)carbon-yl{dicyclo-hex- yl[4-(dimethyl-amino)-phen-yl]phosphane-κP}rhodium(I)

Wade L. Davis; Reinout Meijboom

doi:10.1107/S1600536811050483

(Acetyl-acetonato-κ² O,O′)carbon-yl{dicyclo-hex- yl[4-(dimethyl-amino)-phen-yl]phosphane-κP}rhodium(I)

Wade L. Davis, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, [Rh(C₅H₇O₂)(C ₂₀H₃₂NP)(CO)], features an acetyl-acetonate-chelated Rh^I cation coordinated by one P [Rh - P = 2.2525 (7) Å], one carbonyl C [Rh - C = 1.792 (3) Å] and two O [Rh - O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol-ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh-acetyl-acetonate backbone.

Original language	English
Pages (from-to)	m1874
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811050483
Publication status	Published - Dec 2011

Keywords

R factor = 0.029
T = 100 K
data-to-parameter ratio = 14.7
mean σ(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.076

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811050483

Cite this

@article{50002f86366f4c6991e900e1e6dbecbb,

title = "(Acetyl-acetonato-κ2 O,O′)carbon-yl{dicyclo-hex- yl[4-(dimethyl-amino)-phen-yl]phosphane-κP}rhodium(I)",

abstract = "The title compound, [Rh(C5H7O2)(C 20H32NP)(CO)], features an acetyl-acetonate-chelated RhI cation coordinated by one P [Rh - P = 2.2525 (7) {\AA}], one carbonyl C [Rh - C = 1.792 (3) {\AA}] and two O [Rh - O = 2.0582 (17) and 2.0912 (18) {\AA}] atoms in a slightly distorted square-planar geometry. Mol-ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh-acetyl-acetonate backbone.",

keywords = "R factor = 0.029, T = 100 K, data-to-parameter ratio = 14.7, mean σ(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.076",

author = "Davis, {Wade L.} and Reinout Meijboom",

year = "2011",

month = dec,

doi = "10.1107/S1600536811050483",

language = "English",

volume = "67",

pages = "m1874",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - (Acetyl-acetonato-κ2 O,O′)carbon-yl{dicyclo-hex- yl[4-(dimethyl-amino)-phen-yl]phosphane-κP}rhodium(I)

AU - Davis, Wade L.

AU - Meijboom, Reinout

PY - 2011/12

Y1 - 2011/12

N2 - The title compound, [Rh(C5H7O2)(C 20H32NP)(CO)], features an acetyl-acetonate-chelated RhI cation coordinated by one P [Rh - P = 2.2525 (7) Å], one carbonyl C [Rh - C = 1.792 (3) Å] and two O [Rh - O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol-ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh-acetyl-acetonate backbone.

AB - The title compound, [Rh(C5H7O2)(C 20H32NP)(CO)], features an acetyl-acetonate-chelated RhI cation coordinated by one P [Rh - P = 2.2525 (7) Å], one carbonyl C [Rh - C = 1.792 (3) Å] and two O [Rh - O = 2.0582 (17) and 2.0912 (18) Å] atoms in a slightly distorted square-planar geometry. Mol-ecules are packed in positions of least steric hindrance, with the phosphane ligands positioned above and below the Rh-acetyl-acetonate backbone.

KW - R factor = 0.029

KW - T = 100 K

KW - data-to-parameter ratio = 14.7

KW - mean σ(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.076

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U2 - 10.1107/S1600536811050483

DO - 10.1107/S1600536811050483

M3 - Article

AN - SCOPUS:83155161067

SN - 1600-5368

VL - 67

SP - m1874

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -