(Acetyl-acetonato-κ 2 O,O′)carbon-yl[tris-(4-chloro- phen-yl)phosphane-P]rhodium(I)

Nathan C. Antonels; Reinout Meijboom

doi:10.1107/S1600536812012536

(Acetyl-acetonato-κ ² O,O′)carbon-yl[tris-(4-chloro- phen-yl)phosphane-P]rhodium(I)

Nathan C. Antonels, Reinout Meijboom

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Rh(C ₅H ₇O ₂)(C ₁₈H ₁₂Cl ₃P)(CO)], contains the bidentate acetyl-acetonate ligand coordinated to the Rh ^I atom, forming a chelate ring [Rh-O = 2.0327 (15) and 2.0613 (14) Å]. The Rh ^I atom is additionally coordinated by one P [Rh-P = 2.2281 (6) Å] and one carbonyl C [Rh-C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The mol-ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.

Original language	English
Pages (from-to)	m509
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	4
DOIs	https://doi.org/10.1107/S1600536812012536
Publication status	Published - Apr 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(Acetyl-acetonato-κ 2 O,O′)carbon-yl[tris-(4-chloro- phen-yl)phosphane-P]rhodium(I)",

abstract = "The title compound, [Rh(C 5H 7O 2)(C 18H 12Cl 3P)(CO)], contains the bidentate acetyl-acetonate ligand coordinated to the Rh I atom, forming a chelate ring [Rh-O = 2.0327 (15) and 2.0613 (14) {\AA}]. The Rh I atom is additionally coordinated by one P [Rh-P = 2.2281 (6) {\AA}] and one carbonyl C [Rh-C = 1.812 (2) {\AA}] atom, resulting in a slightly distorted square-planar geometry. The mol-ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.",

author = "Antonels, {Nathan C.} and Reinout Meijboom",

year = "2012",

month = apr,

doi = "10.1107/S1600536812012536",

language = "English",

volume = "68",

pages = "m509",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

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T1 - (Acetyl-acetonato-κ 2 O,O′)carbon-yl[tris-(4-chloro- phen-yl)phosphane-P]rhodium(I)

AU - Antonels, Nathan C.

AU - Meijboom, Reinout

PY - 2012/4

Y1 - 2012/4

N2 - The title compound, [Rh(C 5H 7O 2)(C 18H 12Cl 3P)(CO)], contains the bidentate acetyl-acetonate ligand coordinated to the Rh I atom, forming a chelate ring [Rh-O = 2.0327 (15) and 2.0613 (14) Å]. The Rh I atom is additionally coordinated by one P [Rh-P = 2.2281 (6) Å] and one carbonyl C [Rh-C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The mol-ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.

AB - The title compound, [Rh(C 5H 7O 2)(C 18H 12Cl 3P)(CO)], contains the bidentate acetyl-acetonate ligand coordinated to the Rh I atom, forming a chelate ring [Rh-O = 2.0327 (15) and 2.0613 (14) Å]. The Rh I atom is additionally coordinated by one P [Rh-P = 2.2281 (6) Å] and one carbonyl C [Rh-C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The mol-ecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.

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U2 - 10.1107/S1600536812012536

DO - 10.1107/S1600536812012536

M3 - Article

AN - SCOPUS:84860277550

SN - 1600-5368

VL - 68

SP - m509

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

(Acetyl-acetonato-κ ² O,O′)carbon-yl[tris-(4-chloro- phen-yl)phosphane-P]rhodium(I)

Abstract

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