A phosphorus analogue of bis(η4-cyclobutadiene)iron(0)

Robert Wolf; J. Chris Slootweg; Andreas W. Ehlers; František Hartl; Bas De Bruin; Martin Lutz; Anthony L. Spek; Koop Lammertsma

doi:10.1002/anie.200805193

A phosphorus analogue of bis(η⁴-cyclobutadiene)iron(0)

Robert Wolf, J. Chris Slootweg, Andreas W. Ehlers, František Hartl, Bas De Bruin, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

P makes it possible: The convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(η⁴-P₂C ₂tBu₂)₂] (see structure) suggests that the elusive all-carbon complex [Fe(η⁴-C₄H ₄)₂] is a viable synthetic target.

Original language	English
Pages (from-to)	3104-3107
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	17
DOIs	https://doi.org/10.1002/anie.200805193
Publication status	Published - 14 Apr 2009
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200805193

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abstract = "P makes it possible: The convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(η4-P2C 2tBu2)2] (see structure) suggests that the elusive all-carbon complex [Fe(η4-C4H 4)2] is a viable synthetic target.",

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AU - Ehlers, Andreas W.

AU - Hartl, František

AU - Bruin, Bas De

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Lammertsma, Koop

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AB - P makes it possible: The convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(η4-P2C 2tBu2)2] (see structure) suggests that the elusive all-carbon complex [Fe(η4-C4H 4)2] is a viable synthetic target.

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A phosphorus analogue of bis(η⁴-cyclobutadiene)iron(0)

Abstract

ASJC Scopus subject areas

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