A novel CSiP ring from the reaction of a complexed phosphinidene and a silene

Mark J.M. Vlaar; Andreas W. Ehlers; Frans J.J. de Kanter; Marius Schakel; Anthony L. Spek; Martin Lutz; Nadejda Sigal; Yitzhak Apeloig; Koop Lammertsma

doi:10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B

A novel CSiP ring from the reaction of a complexed phosphinidene and a silene

Mark J.M. Vlaar
, Andreas W. Ehlers
, Frans J.J. de Kanter
, Marius Schakel
, Anthony L. Spek
, Martin Lutz
, Nadejda Sigal
, Yitzhak Apeloig
, Koop Lammertsma

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A phosphasilirane was synthesized from the addition of a terminal phosphinidene complex with a silene [Eq. (1)]. Both starting materials are reactive intermediates that are simultaneously generated in situ. The first X-ray structure analysis of a complexed phosphasilirane and the calculated strain energy for the parent system give insight into the stability of this new CPSi ring system.

Original language	English
Pages (from-to)	4127-4130
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	22
DOIs	https://doi.org/10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B
Publication status	Published - 17 Nov 2000
Externally published	Yes

Keywords

Phosphorus heterocycles
Silenes
Silicon heterocycles
Small ring systems

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B

Cite this

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title = "A novel CSiP ring from the reaction of a complexed phosphinidene and a silene",

abstract = "A phosphasilirane was synthesized from the addition of a terminal phosphinidene complex with a silene [Eq. (1)]. Both starting materials are reactive intermediates that are simultaneously generated in situ. The first X-ray structure analysis of a complexed phosphasilirane and the calculated strain energy for the parent system give insight into the stability of this new CPSi ring system.",

keywords = "Phosphorus heterocycles, Silenes, Silicon heterocycles, Small ring systems",

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year = "2000",

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doi = "10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B",

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pages = "4127--4130",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - A novel CSiP ring from the reaction of a complexed phosphinidene and a silene

AU - Vlaar, Mark J.M.

AU - Ehlers, Andreas W.

AU - de Kanter, Frans J.J.

AU - Schakel, Marius

AU - Spek, Anthony L.

AU - Lutz, Martin

AU - Sigal, Nadejda

AU - Apeloig, Yitzhak

AU - Lammertsma, Koop

PY - 2000/11/17

Y1 - 2000/11/17

N2 - A phosphasilirane was synthesized from the addition of a terminal phosphinidene complex with a silene [Eq. (1)]. Both starting materials are reactive intermediates that are simultaneously generated in situ. The first X-ray structure analysis of a complexed phosphasilirane and the calculated strain energy for the parent system give insight into the stability of this new CPSi ring system.

AB - A phosphasilirane was synthesized from the addition of a terminal phosphinidene complex with a silene [Eq. (1)]. Both starting materials are reactive intermediates that are simultaneously generated in situ. The first X-ray structure analysis of a complexed phosphasilirane and the calculated strain energy for the parent system give insight into the stability of this new CPSi ring system.

KW - Phosphorus heterocycles

KW - Silenes

KW - Silicon heterocycles

KW - Small ring systems

UR - https://www.scopus.com/pages/publications/0034680551

U2 - 10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B

DO - 10.1002/1521-3773(20001117)39:22<4127::AID-ANIE4127>3.0.CO;2-B

M3 - Article

AN - SCOPUS:0034680551

SN - 1433-7851

VL - 39

SP - 4127

EP - 4130

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

A novel CSiP ring from the reaction of a complexed phosphinidene and a silene

Abstract

Keywords

ASJC Scopus subject areas

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