A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)

Reinout Meijboom; Alfred Muller; Andreas Roodt

doi:10.1107/S1600536806015637

A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)

Reinout Meijboom, Alfred Muller, Andreas Roodt

University of The Free State

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, trans-[RhCl{P(4-FC₆H₄) ₃}₂(CO)], where 4-FC₆H₄ is 4-fluorophenyl, the Rh - P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh - Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (θ_E) for the phosphine ligands were calculated to be 155 and 156°.

Original language	English
Pages (from-to)	m1309-m1311
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	6
DOIs	https://doi.org/10.1107/S1600536806015637
Publication status	Published - Jun 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)",

abstract = "In the title compound, trans-[RhCl\{P(4-FC6H4) 3\}2(CO)], where 4-FC6H4 is 4-fluorophenyl, the Rh - P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) {\AA}, and the Rh - Cl bond distances are 2.3689 (5) and 2.3694 (5) {\AA}. The effective cone angles (θE) for the phosphine ligands were calculated to be 155 and 156°.",

author = "Reinout Meijboom and Alfred Muller and Andreas Roodt",

year = "2006",

month = jun,

doi = "10.1107/S1600536806015637",

language = "English",

volume = "62",

pages = "m1309--m1311",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

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T1 - A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)

AU - Meijboom, Reinout

AU - Muller, Alfred

AU - Roodt, Andreas

PY - 2006/6

Y1 - 2006/6

N2 - In the title compound, trans-[RhCl{P(4-FC6H4) 3}2(CO)], where 4-FC6H4 is 4-fluorophenyl, the Rh - P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh - Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (θE) for the phosphine ligands were calculated to be 155 and 156°.

AB - In the title compound, trans-[RhCl{P(4-FC6H4) 3}2(CO)], where 4-FC6H4 is 4-fluorophenyl, the Rh - P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh - Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (θE) for the phosphine ligands were calculated to be 155 and 156°.

UR - https://www.scopus.com/pages/publications/33744999387

U2 - 10.1107/S1600536806015637

DO - 10.1107/S1600536806015637

M3 - Article

AN - SCOPUS:33744999387

SN - 1600-5368

VL - 62

SP - m1309-m1311

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)

Abstract

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