A new polymorph of trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine] rhodium(I)

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Abstract

In the title compound, trans-[RhCl{P(4-FC6H4) 3}2(CO)], where 4-FC6H4 is 4-fluorophenyl, the Rh - P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh - Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (θE) for the phosphine ligands were calculated to be 155 and 156°.

Original languageEnglish
Pages (from-to)m1309-m1311
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number6
DOIs
Publication statusPublished - Jun 2006
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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