A new method for selective protection of two hydroxyl groups in carbohydrates, glycals in particular

Cedric W. Holzapfel; Johan J. Huyser; Thilo L. van der Merwe; Fanie R. van Heerden

doi:10.3987/com-91-5757

A new method for selective protection of two hydroxyl groups in carbohydrates, glycals in particular

Cedric W. Holzapfel, Johan J. Huyser, Thilo L. van der Merwe, Fanie R. van Heerden

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The regioselective conversion of selected carbohydrate derivatives into their allylic cyclic acetals was achieved by successive treatment with dibutyltin oxide, acrolein diacetate and catalytic amount of tetrakis(triphenylphosphine)palladium(0). Methods for the removal of the new protecting group are discussed.

Original language	English
Pages (from-to)	1445-1450
Number of pages	6
Journal	Heterocycles
Volume	32
Issue number	8
DOIs	https://doi.org/10.3987/com-91-5757
Publication status	Published - 1 Aug 1991

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/com-91-5757

Cite this

@article{5c97904dabb14ef3bbdfcb3d733da1a4,

title = "A new method for selective protection of two hydroxyl groups in carbohydrates, glycals in particular",

abstract = "The regioselective conversion of selected carbohydrate derivatives into their allylic cyclic acetals was achieved by successive treatment with dibutyltin oxide, acrolein diacetate and catalytic amount of tetrakis(triphenylphosphine)palladium(0). Methods for the removal of the new protecting group are discussed.",

author = "Holzapfel, {Cedric W.} and Huyser, {Johan J.} and {van der Merwe}, {Thilo L.} and {van Heerden}, {Fanie R.}",

year = "1991",

month = aug,

day = "1",

doi = "10.3987/com-91-5757",

language = "English",

volume = "32",

pages = "1445--1450",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "8",

}

TY - JOUR

T1 - A new method for selective protection of two hydroxyl groups in carbohydrates, glycals in particular

AU - Holzapfel, Cedric W.

AU - Huyser, Johan J.

AU - van der Merwe, Thilo L.

AU - van Heerden, Fanie R.

PY - 1991/8/1

Y1 - 1991/8/1

N2 - The regioselective conversion of selected carbohydrate derivatives into their allylic cyclic acetals was achieved by successive treatment with dibutyltin oxide, acrolein diacetate and catalytic amount of tetrakis(triphenylphosphine)palladium(0). Methods for the removal of the new protecting group are discussed.

AB - The regioselective conversion of selected carbohydrate derivatives into their allylic cyclic acetals was achieved by successive treatment with dibutyltin oxide, acrolein diacetate and catalytic amount of tetrakis(triphenylphosphine)palladium(0). Methods for the removal of the new protecting group are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0010338324&partnerID=8YFLogxK

U2 - 10.3987/com-91-5757

DO - 10.3987/com-91-5757

M3 - Article

AN - SCOPUS:0010338324

SN - 0385-5414

VL - 32

SP - 1445

EP - 1450

JO - Heterocycles

JF - Heterocycles

IS - 8

ER -

A new method for selective protection of two hydroxyl groups in carbohydrates, glycals in particular

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this