A facile route to steroidal 6-deoxy-α-L-allopyranosides

Fanie R. Van Heerden; John T. Dixon; Cedric W. Holzapfel

doi:10.1080/00397919808004442

A facile route to steroidal 6-deoxy-α-L-allopyranosides

Fanie R. Van Heerden, John T. Dixon, Cedric W. Holzapfel

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cisdiol via an intermediate bromohydrin.

Original language	English
Pages (from-to)	3345-3357
Number of pages	13
Journal	Synthetic Communications
Volume	28
Issue number	18
DOIs	https://doi.org/10.1080/00397919808004442
Publication status	Published - 1998

ASJC Scopus subject areas

Organic Chemistry

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10.1080/00397919808004442

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title = "A facile route to steroidal 6-deoxy-α-L-allopyranosides",

abstract = "The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cisdiol via an intermediate bromohydrin.",

author = "\{Van Heerden\}, \{Fanie R.\} and Dixon, \{John T.\} and Holzapfel, \{Cedric W.\}",

year = "1998",

doi = "10.1080/00397919808004442",

language = "English",

volume = "28",

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journal = "Synthetic Communications",

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T1 - A facile route to steroidal 6-deoxy-α-L-allopyranosides

AU - Van Heerden, Fanie R.

AU - Dixon, John T.

AU - Holzapfel, Cedric W.

PY - 1998

Y1 - 1998

N2 - The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cisdiol via an intermediate bromohydrin.

AB - The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cisdiol via an intermediate bromohydrin.

UR - https://www.scopus.com/pages/publications/0031782229

U2 - 10.1080/00397919808004442

DO - 10.1080/00397919808004442

M3 - Article

AN - SCOPUS:0031782229

SN - 0039-7911

VL - 28

SP - 3345

EP - 3357

JO - Synthetic Communications

JF - Synthetic Communications

IS - 18

ER -

A facile route to steroidal 6-deoxy-α-L-allopyranosides

Abstract

ASJC Scopus subject areas

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