A facile non-organometallic synthesis of hexadecylamine-capped ZnSe nanoparticles

Oluwatobi S. Oluwafemi; Vuyelwa Ncapayi; Oseyemi Olubomehin; Otolorin A. Osibote; Sandile P. Songca

doi:10.1016/j.mssp.2014.07.007

A facile non-organometallic synthesis of hexadecylamine-capped ZnSe nanoparticles

Oluwatobi S. Oluwafemi, Vuyelwa Ncapayi, Oseyemi Olubomehin, Otolorin A. Osibote, Sandile P. Songca

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The synthesis of hexadecylamine (HDA)-capped ZnSe nanoparticles via a facile method that is not mediated by organometallic compounds at low temperature is hereby reported. The synthesis involves the addition of an aqueous solution of zinc chloride to a selenide ion solution prepared by the reduction of selenium powder. By varying the reduction time, we studied the size, optical and structural properties of the as-synthesised nanoparticles. The as-synthesised ZnSe nanocrystals were characterised by UV-visible (UV-vis) absorption and PL spectroscopy, transmission electron microcopy (TEM), high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). All the particles exhibited strong quantum confinement in their optical properties with band-edge luminescence.

Original language	English
Pages (from-to)	427-432
Number of pages	6
Journal	Materials Science in Semiconductor Processing
Volume	27
Issue number	1
DOIs	https://doi.org/10.1016/j.mssp.2014.07.007
Publication status	Published - Nov 2014
Externally published	Yes

Keywords

Hexadecylamine
Nanoparticles
Optical spectroscopy
Quantum confinement
X-ray diffraction
ZnSe

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/j.mssp.2014.07.007

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title = "A facile non-organometallic synthesis of hexadecylamine-capped ZnSe nanoparticles",

abstract = "The synthesis of hexadecylamine (HDA)-capped ZnSe nanoparticles via a facile method that is not mediated by organometallic compounds at low temperature is hereby reported. The synthesis involves the addition of an aqueous solution of zinc chloride to a selenide ion solution prepared by the reduction of selenium powder. By varying the reduction time, we studied the size, optical and structural properties of the as-synthesised nanoparticles. The as-synthesised ZnSe nanocrystals were characterised by UV-visible (UV-vis) absorption and PL spectroscopy, transmission electron microcopy (TEM), high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). All the particles exhibited strong quantum confinement in their optical properties with band-edge luminescence.",

keywords = "Hexadecylamine, Nanoparticles, Optical spectroscopy, Quantum confinement, X-ray diffraction, ZnSe",

author = "Oluwafemi, \{Oluwatobi S.\} and Vuyelwa Ncapayi and Oseyemi Olubomehin and Osibote, \{Otolorin A.\} and Songca, \{Sandile P.\}",

year = "2014",

month = nov,

doi = "10.1016/j.mssp.2014.07.007",

language = "English",

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pages = "427--432",

journal = "Materials Science in Semiconductor Processing",

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AU - Oluwafemi, Oluwatobi S.

AU - Ncapayi, Vuyelwa

AU - Olubomehin, Oseyemi

AU - Osibote, Otolorin A.

AU - Songca, Sandile P.

PY - 2014/11

Y1 - 2014/11

N2 - The synthesis of hexadecylamine (HDA)-capped ZnSe nanoparticles via a facile method that is not mediated by organometallic compounds at low temperature is hereby reported. The synthesis involves the addition of an aqueous solution of zinc chloride to a selenide ion solution prepared by the reduction of selenium powder. By varying the reduction time, we studied the size, optical and structural properties of the as-synthesised nanoparticles. The as-synthesised ZnSe nanocrystals were characterised by UV-visible (UV-vis) absorption and PL spectroscopy, transmission electron microcopy (TEM), high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). All the particles exhibited strong quantum confinement in their optical properties with band-edge luminescence.

AB - The synthesis of hexadecylamine (HDA)-capped ZnSe nanoparticles via a facile method that is not mediated by organometallic compounds at low temperature is hereby reported. The synthesis involves the addition of an aqueous solution of zinc chloride to a selenide ion solution prepared by the reduction of selenium powder. By varying the reduction time, we studied the size, optical and structural properties of the as-synthesised nanoparticles. The as-synthesised ZnSe nanocrystals were characterised by UV-visible (UV-vis) absorption and PL spectroscopy, transmission electron microcopy (TEM), high-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). All the particles exhibited strong quantum confinement in their optical properties with band-edge luminescence.

KW - Hexadecylamine

KW - Nanoparticles

KW - Optical spectroscopy

KW - Quantum confinement

KW - X-ray diffraction

KW - ZnSe

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DO - 10.1016/j.mssp.2014.07.007

M3 - Article

AN - SCOPUS:84905497839

SN - 1369-8001

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JO - Materials Science in Semiconductor Processing

JF - Materials Science in Semiconductor Processing

IS - 1

ER -

A facile non-organometallic synthesis of hexadecylamine-capped ZnSe nanoparticles

Abstract

Keywords

ASJC Scopus subject areas

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