A diorganotin(IV) complex with pyrazine-2-carbaldehyde 4- ethylthiosemicarbazone

Ramaiyer Venkatraman; Lungile Sitole; Tamarea D. Adams; Joseph A. Cameron; Frank R. Fronczek

doi:10.1107/S1600536807035052

A diorganotin(IV) complex with pyrazine-2-carbaldehyde 4- ethylthiosemicarbazone

Ramaiyer Venkatraman
, Lungile Sitole
, Tamarea D. Adams
, Joseph A. Cameron
, Frank R. Fronczek

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The reaction of pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone (Hapetsc) with diphenyl-tin(IV) dichloride in ethanol resulted in the formation of the title compound, dichloridodiphenyl-bis(pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone)tin(IV), [Sn(C6H5)2Cl2(C9H13N5S)2]. The complex exhibits a distorted octa-hedron about the Sn atom, which lies on an inversion center and is coordinated by two Cl atoms, two phenyl ligands and two Hapetsc units. The pyrazine ligands are in a trans configuration and behave as monodentate donors through their ring N atoms. The Sn - Cl distances are 2.5484 (4) Å, the Sn - C distances are 2.1378 (12) Å and the Sn - N distances are 2.4032 (11) Å. One NH group of the thio-semicarbazone ligand forms an intra-molecular S(5) hydrogen bond with an adjacent N atom on the same ligand. The other N - H group is not involved in hydrogen bonding.

Original language	English
Pages (from-to)	m2212-m2213
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	8
DOIs	https://doi.org/10.1107/S1600536807035052
Publication status	Published - 31 Jul 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536807035052

Cite this

@article{25bb64ed962b44b1953df9a1bbb5f1aa,

title = "A diorganotin(IV) complex with pyrazine-2-carbaldehyde 4- ethylthiosemicarbazone",

abstract = "The reaction of pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone (Hapetsc) with diphenyl-tin(IV) dichloride in ethanol resulted in the formation of the title compound, dichloridodiphenyl-bis(pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone)tin(IV), [Sn(C6H5)2Cl2(C9H13N5S)2]. The complex exhibits a distorted octa-hedron about the Sn atom, which lies on an inversion center and is coordinated by two Cl atoms, two phenyl ligands and two Hapetsc units. The pyrazine ligands are in a trans configuration and behave as monodentate donors through their ring N atoms. The Sn - Cl distances are 2.5484 (4) {\AA}, the Sn - C distances are 2.1378 (12) {\AA} and the Sn - N distances are 2.4032 (11) {\AA}. One NH group of the thio-semicarbazone ligand forms an intra-molecular S(5) hydrogen bond with an adjacent N atom on the same ligand. The other N - H group is not involved in hydrogen bonding.",

author = "Ramaiyer Venkatraman and Lungile Sitole and Adams, \{Tamarea D.\} and Cameron, \{Joseph A.\} and Fronczek, \{Frank R.\}",

year = "2007",

month = jul,

day = "31",

doi = "10.1107/S1600536807035052",

language = "English",

volume = "63",

pages = "m2212--m2213",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - A diorganotin(IV) complex with pyrazine-2-carbaldehyde 4- ethylthiosemicarbazone

AU - Venkatraman, Ramaiyer

AU - Sitole, Lungile

AU - Adams, Tamarea D.

AU - Cameron, Joseph A.

AU - Fronczek, Frank R.

PY - 2007/7/31

Y1 - 2007/7/31

N2 - The reaction of pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone (Hapetsc) with diphenyl-tin(IV) dichloride in ethanol resulted in the formation of the title compound, dichloridodiphenyl-bis(pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone)tin(IV), [Sn(C6H5)2Cl2(C9H13N5S)2]. The complex exhibits a distorted octa-hedron about the Sn atom, which lies on an inversion center and is coordinated by two Cl atoms, two phenyl ligands and two Hapetsc units. The pyrazine ligands are in a trans configuration and behave as monodentate donors through their ring N atoms. The Sn - Cl distances are 2.5484 (4) Å, the Sn - C distances are 2.1378 (12) Å and the Sn - N distances are 2.4032 (11) Å. One NH group of the thio-semicarbazone ligand forms an intra-molecular S(5) hydrogen bond with an adjacent N atom on the same ligand. The other N - H group is not involved in hydrogen bonding.

AB - The reaction of pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone (Hapetsc) with diphenyl-tin(IV) dichloride in ethanol resulted in the formation of the title compound, dichloridodiphenyl-bis(pyrazine-2-carbaldehyde 4-ethyl-thio-semi-carbazone)tin(IV), [Sn(C6H5)2Cl2(C9H13N5S)2]. The complex exhibits a distorted octa-hedron about the Sn atom, which lies on an inversion center and is coordinated by two Cl atoms, two phenyl ligands and two Hapetsc units. The pyrazine ligands are in a trans configuration and behave as monodentate donors through their ring N atoms. The Sn - Cl distances are 2.5484 (4) Å, the Sn - C distances are 2.1378 (12) Å and the Sn - N distances are 2.4032 (11) Å. One NH group of the thio-semicarbazone ligand forms an intra-molecular S(5) hydrogen bond with an adjacent N atom on the same ligand. The other N - H group is not involved in hydrogen bonding.

UR - https://www.scopus.com/pages/publications/34547820356

U2 - 10.1107/S1600536807035052

DO - 10.1107/S1600536807035052

M3 - Article

AN - SCOPUS:34547820356

SN - 1600-5368

VL - 63

SP - m2212-m2213

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

A diorganotin(IV) complex with pyrazine-2-carbaldehyde 4- ethylthiosemicarbazone

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this