A CO2 capture technology using multi-walled carbon nanotubes with polyaspartamide surfactant

Jacob M. Ngoy, Nicola Wagner, Luca Riboldi, Olav Bolland

Research output: Contribution to journalConference articlepeer-review

79 Citations (Scopus)

Abstract

Global climate change resulting from the emission of greenhouse gases has become a widespread concern in the recent years. Carbon dioxide alone contributes roughly two-thirds to the enhanced greenhouse effect. Carbon capture and storage (CCS), an approach for mitigating potential global climate change, is widely known as a selected track towards sustainable application of fossil fuels. Technologies to separate and compress CO2 from power plant flue gases are commercially available. Absorption, using monoethanolamine (MEA), is the most common technology applied to capture CO2 from flue gas of fossil fuel power plants. However, the efficiency penalty induced by carbon capture within energy conversion systems poses a threat to the economic viability of these systems. The adsorption technology due to the ability to operate at moderate temperature and pressure, the increase of the capacity of CO2 adsorption and the compliance with the environmental safety are the trickiest in the adsorbent design. The primary objective of this work was to design an adsorbent with ability of adsorbing large quantity CO2 at efficient energy. A long chain polymer was grafted with a diamine to provide a large CO2 anchoring site for carbamate formation, covering multiwalled carbon nanotubes (MWNTs) to enhance the surface area and pore volume. Thus, an advanced adsorbent was made after polycondensation of aspartic acid between 190°C-210°C in phosphoric acid medium and the use of dicyclohexylcarbodiimide (DCC) as the coupling agent; this resulted in long chain polysuccinimide (PSI) synthesis. A ethylenediamine (EDA) was grafted to the PSI to give a polyaspartamide (PAA), which, covering the MWNTs, has achieved an adsorbent with 100% EDA incorporation as showed 1H NMR. The chemical surface of the PAA-MWNTs showed with FTIR analysis the primary amine group and the amide group as CO2 anchoring sites and biodegradable bonds respectively. As evaluated via BET, the low surface area and pore volume of PAA have increased by 31 and 41 times respectively with the inclusion of MWNTs (8nm). Thus, the surface area, pore volume, and pore size of the synthesized adsorbent (PAA-MWNTs) were 60.4m2/g, 0.4cm3/ respectively. Transmission electron microscope (TEM) analysis and the decrease of graphitized carbon as shown with Raman spectra have shown that the covering of MWNTs by the polymer PAA increased the diameter size from 8nm to 15nm. The TGA analysis showed a 200°C temperature limit for CO2 adsorption using PAA-MWNTs as an adsorbent. The CO: Adsorption isotherm was completed at 25°C with the use of TGA in order to evaluate the CO2 adsorption capacity of the adsorbents. The PAA-MWNTs showed a higher CO2 adsorption capacity of 70gCO2/kg compared to PAA, PSI, and MWNTs alone, where the adsorption capacity showed 46.17gCO2/kg, 26.90gCO2/kg, and 15.20gCO2/kg respectively.

Original languageEnglish
Pages (from-to)2230-2248
Number of pages19
JournalEnergy Procedia
Volume63
DOIs
Publication statusPublished - 2014
Externally publishedYes
Event12th International Conference on Greenhouse Gas Control Technologies, GHGT 2014 - Austin, United States
Duration: 5 Oct 20149 Oct 2014

Keywords

  • Multi-walled carbon nanotubes
  • Polyaspartamide and CO adsorption

ASJC Scopus subject areas

  • General Energy

Fingerprint

Dive into the research topics of 'A CO2 capture technology using multi-walled carbon nanotubes with polyaspartamide surfactant'. Together they form a unique fingerprint.

Cite this