A comparative study on structural, morphological and luminescence characteristics of Zn 3(VO 4) 2 phosphor prepared via hydrothermal and citrate-gel combustion routes

Shreyas S. Pitale, Mukut Gohain, I. M. Nagpure, O. M. Ntwaeaborwa, Barend C.B. Bezuidenhoudt, H. C. Swart

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)

Abstract

Comparison of structural, morphological and spectroscopic properties of zinc vanadate Zn 3(VO 4) 2 phosphor synthesized via two different methods, viz. citrate-gel combustion and hydrothermal reaction, is presented. Highly crystalline and pure phase micro-rods are achieved by citrate-gel combustion route. The hydrothermal reaction products exhibit ribbon like structures. X-ray photoelectron spectroscopic investigation reveals the presence of multiple oxidation states of vanadium in the hydrothermally synthesized phosphor. Luminescence properties have also been compared and the effect of divalent cationic substitution (Ca, Mg) is presented.

Original languageEnglish
Pages (from-to)1485-1488
Number of pages4
JournalPhysica B: Condensed Matter
Volume407
Issue number10
DOIs
Publication statusPublished - 15 May 2012
Externally publishedYes

Keywords

  • Citrate-gel combustion
  • Divalent cationic substitution
  • Hydrothermal
  • Zn (VO )

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

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