[4-(Dimethylamino)phenyl]sdiphenylphosphine selenide

Wade L. Davis; Alfred Muller

doi:10.1107/S1600536812042602

[4-(Dimethylamino)phenyl]sdiphenylphosphine selenide

Wade L. Davis, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, C₂0H₂₀NPSe, the P atom lies in a distorted tetrahedral environment. The Tolman cone angle is 157°indicating steric crowding at this atom. In the crystal, weak C-H⋯Se interactions create linked dimeric units and C-H⋯π interactions are also observed.

Original language	English
Pages (from-to)	o3153-o3154
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	11
DOIs	https://doi.org/10.1107/S1600536812042602
Publication status	Published - Nov 2012

Keywords

R factor = 0.036
T = 100 K
data-to-parameter ratio = 21.7
mean ̄(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.097

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "[4-(Dimethylamino)phenyl]sdiphenylphosphine selenide",

abstract = "In the title compound, C20H20NPSe, the P atom lies in a distorted tetrahedral environment. The Tolman cone angle is 157°indicating steric crowding at this atom. In the crystal, weak C-H⋯Se interactions create linked dimeric units and C-H⋯π interactions are also observed.",

keywords = "R factor = 0.036, T = 100 K, data-to-parameter ratio = 21.7, mean{\= }(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.097",

author = "Davis, {Wade L.} and Alfred Muller",

year = "2012",

month = nov,

doi = "10.1107/S1600536812042602",

language = "English",

volume = "68",

pages = "o3153--o3154",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - [4-(Dimethylamino)phenyl]sdiphenylphosphine selenide

AU - Davis, Wade L.

AU - Muller, Alfred

PY - 2012/11

Y1 - 2012/11

N2 - In the title compound, C20H20NPSe, the P atom lies in a distorted tetrahedral environment. The Tolman cone angle is 157°indicating steric crowding at this atom. In the crystal, weak C-H⋯Se interactions create linked dimeric units and C-H⋯π interactions are also observed.

AB - In the title compound, C20H20NPSe, the P atom lies in a distorted tetrahedral environment. The Tolman cone angle is 157°indicating steric crowding at this atom. In the crystal, weak C-H⋯Se interactions create linked dimeric units and C-H⋯π interactions are also observed.

KW - R factor = 0.036

KW - T = 100 K

KW - data-to-parameter ratio = 21.7

KW - mean ̄(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.097

UR - http://www.scopus.com/inward/record.url?scp=84870926782&partnerID=8YFLogxK

U2 - 10.1107/S1600536812042602

DO - 10.1107/S1600536812042602

M3 - Article

AN - SCOPUS:84870926782

SN - 1600-5368

VL - 68

SP - o3153-o3154

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

[4-(Dimethylamino)phenyl]sdiphenylphosphine selenide

Abstract

Keywords

ASJC Scopus subject areas

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