(4-Chlorobenzenethiolato-S)(η 5-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

James Darkwa; Wolfgang Milius

doi:10.1107/S0108270196005896

(4-Chlorobenzenethiolato-S)(η ⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

James Darkwa, Wolfgang Milius

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The Ni atom in [Ni(C₆H₄ClS)(C₅H₅)(C ₁₈H₁₅P)] has a distorted trigonal geometry, with bond angles Cp-Ni-S 132.3 (1), Cp-Ni-P 135.3 (5) and P-Ni-S 92.4(1)°, where Cp represents the centroid of the C₅H₅ ring. The bond distances Cp-Ni, Ni-S and Ni-P are 1.763 (1), 2.190 (1) and 2.144 (1) Å, respectively, which are close to distances found in similar compounds. A structural model with disordered cyclopentadienyl ligands was used.

Original language	English
Pages (from-to)	2159-2161
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	9
DOIs	https://doi.org/10.1107/S0108270196005896
Publication status	Published - 15 Sept 1996
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "(4-Chlorobenzenethiolato-S)(η 5-cyclopentadienyl)(triphenylphosphine-P)nickel(II)",

abstract = "The Ni atom in [Ni(C6H4ClS)(C5H5)(C 18H15P)] has a distorted trigonal geometry, with bond angles Cp-Ni-S 132.3 (1), Cp-Ni-P 135.3 (5) and P-Ni-S 92.4(1)°, where Cp represents the centroid of the C5H5 ring. The bond distances Cp-Ni, Ni-S and Ni-P are 1.763 (1), 2.190 (1) and 2.144 (1) {\AA}, respectively, which are close to distances found in similar compounds. A structural model with disordered cyclopentadienyl ligands was used.",

author = "James Darkwa and Wolfgang Milius",

year = "1996",

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doi = "10.1107/S0108270196005896",

language = "English",

volume = "52",

pages = "2159--2161",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

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T1 - (4-Chlorobenzenethiolato-S)(η 5-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

AU - Darkwa, James

AU - Milius, Wolfgang

PY - 1996/9/15

Y1 - 1996/9/15

N2 - The Ni atom in [Ni(C6H4ClS)(C5H5)(C 18H15P)] has a distorted trigonal geometry, with bond angles Cp-Ni-S 132.3 (1), Cp-Ni-P 135.3 (5) and P-Ni-S 92.4(1)°, where Cp represents the centroid of the C5H5 ring. The bond distances Cp-Ni, Ni-S and Ni-P are 1.763 (1), 2.190 (1) and 2.144 (1) Å, respectively, which are close to distances found in similar compounds. A structural model with disordered cyclopentadienyl ligands was used.

AB - The Ni atom in [Ni(C6H4ClS)(C5H5)(C 18H15P)] has a distorted trigonal geometry, with bond angles Cp-Ni-S 132.3 (1), Cp-Ni-P 135.3 (5) and P-Ni-S 92.4(1)°, where Cp represents the centroid of the C5H5 ring. The bond distances Cp-Ni, Ni-S and Ni-P are 1.763 (1), 2.190 (1) and 2.144 (1) Å, respectively, which are close to distances found in similar compounds. A structural model with disordered cyclopentadienyl ligands was used.

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DO - 10.1107/S0108270196005896

M3 - Article

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SN - 0108-2701

VL - 52

SP - 2159

EP - 2161

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

(4-Chlorobenzenethiolato-S)(η ⁵-cyclopentadienyl)(triphenylphosphine-P)nickel(II)

Abstract

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