(3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol- 1-yl)eth-yl]amine

Lara C. Spencer; Ilia A. Guzei; Michael K. Ainooson; James Darkwa

doi:10.1107/S160053681203231X

(3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol- 1-yl)eth-yl]amine

Lara C. Spencer
, Ilia A. Guzei
, Michael K. Ainooson
, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The angles within the benzene ring in the title compound, C30H49N3O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth-oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents.

Original language	English
Pages (from-to)	o2515-o2516
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	8
DOIs	https://doi.org/10.1107/S160053681203231X
Publication status	Published - Aug 2012

Keywords

R factor = 0.046
T = 100 K
data-to-parameter ratio = 16.2
mean σ(C-C) = 0.003 Å
single-crystal X-ray study
wR factor = 0.123

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S160053681203231X

Cite this

@article{e98218f3f1244992a299f850d98ccda3,

title = "(3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol- 1-yl)eth-yl]amine",

abstract = "The angles within the benzene ring in the title compound, C30H49N3O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth-oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents.",

keywords = "R factor = 0.046, T = 100 K, data-to-parameter ratio = 16.2, mean σ(C-C) = 0.003 {\AA}, single-crystal X-ray study, wR factor = 0.123",

author = "Spencer, \{Lara C.\} and Guzei, \{Ilia A.\} and Ainooson, \{Michael K.\} and James Darkwa",

year = "2012",

month = aug,

doi = "10.1107/S160053681203231X",

language = "English",

volume = "68",

pages = "o2515--o2516",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - (3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol- 1-yl)eth-yl]amine

AU - Spencer, Lara C.

AU - Guzei, Ilia A.

AU - Ainooson, Michael K.

AU - Darkwa, James

PY - 2012/8

Y1 - 2012/8

N2 - The angles within the benzene ring in the title compound, C30H49N3O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth-oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents.

AB - The angles within the benzene ring in the title compound, C30H49N3O, ranging from 116.34 (16) to 124.18 (16)°, reflect the presence of electron-donating and electron-withdrawing substituents. The angles at the two electron-donating tert-butyl substituents are smaller than 120°, at the electron-withdrawing eth-oxy substituent larger than 120°, and at the imine substituent equal to 119.59 (16)°. The latter does not reflect the electron-donating nature of the imine group due to the presence of other substituents.

KW - R factor = 0.046

KW - T = 100 K

KW - data-to-parameter ratio = 16.2

KW - mean σ(C-C) = 0.003 Å

KW - single-crystal X-ray study

KW - wR factor = 0.123

UR - https://www.scopus.com/pages/publications/84864675935

U2 - 10.1107/S160053681203231X

DO - 10.1107/S160053681203231X

M3 - Article

AN - SCOPUS:84864675935

SN - 1600-5368

VL - 68

SP - o2515-o2516

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

(3,5-Di-tert-butyl-2-eth-oxy-benzyl-idene)[2-(3,5-di-tert-butyl-1H-pyrazol- 1-yl)eth-yl]amine

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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