[3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction

Renier Crous; Cedric W. Holzapfel; Gert J. Kruger

doi:10.1107/S0108270197017459

[3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction

Renier Crous, Cedric W. Holzapfel, Gert J. Kruger

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The configuration about the Sn centre in the title compound, [Sn(CH₃)₃(C₁₀H₁₃N₂O ₂)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.

Original language	English
Pages (from-to)	760-762
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	6
DOIs	https://doi.org/10.1107/S0108270197017459
Publication status	Published - 15 Jun 1998

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "[3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction",

abstract = "The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O 2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) {\AA} gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.",

author = "Renier Crous and Holzapfel, \{Cedric W.\} and Kruger, \{Gert J.\}",

year = "1998",

month = jun,

day = "15",

doi = "10.1107/S0108270197017459",

language = "English",

volume = "54",

pages = "760--762",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "6",

}

[3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction. / Crous, Renier; Holzapfel, Cedric W.; Kruger, Gert J.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 6, 15.06.1998, p. 760-762.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction

AU - Crous, Renier

AU - Holzapfel, Cedric W.

AU - Kruger, Gert J.

PY - 1998/6/15

Y1 - 1998/6/15

N2 - The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O 2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.

AB - The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O 2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.

UR - https://www.scopus.com/pages/publications/0344599773

U2 - 10.1107/S0108270197017459

DO - 10.1107/S0108270197017459

M3 - Article

AN - SCOPUS:0344599773

SN - 0108-2701

VL - 54

SP - 760

EP - 762

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

[3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction

Abstract

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