TY - JOUR
T1 - [3-(tert-butoxycarbonylamino)-4-pyridyl]-trimethyltin(IV), a tetraorganotin compound containing an unexpected intramolecular Sn⋯O interaction
AU - Crous, Renier
AU - Holzapfel, Cedric W.
AU - Kruger, Gert J.
PY - 1998/6/15
Y1 - 1998/6/15
N2 - The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O 2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.
AB - The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O 2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn⋯O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this is a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.
UR - http://www.scopus.com/inward/record.url?scp=0344599773&partnerID=8YFLogxK
U2 - 10.1107/S0108270197017459
DO - 10.1107/S0108270197017459
M3 - Article
AN - SCOPUS:0344599773
SN - 0108-2701
VL - 54
SP - 760
EP - 762
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 6
ER -