2,3-Bis(3-fluoro-phen-yl)tetra-zolium-5-thiol-ate

Karel G. von Eschwege; Alfred Muller

doi:10.1107/S1600536809026683

2,3-Bis(3-fluoro-phen-yl)tetra-zolium-5-thiol-ate

Karel G. von Eschwege
, Alfred Muller

Chemical Sciences

University of The Free State

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The zwitterionic title compound, C₁₃H₈F ₂N₄S, is situated on a twofold rotation axis running along the C - S [1.691 (2) Å] single bond. The phenyl-ene ring is twisted out of the tetra-zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) Å] between the centroids of the phenyl-ene and tetra-zolium rings of neighbouring mol-ecules suggest π-π inter-actions. The crystal under investigation was a non-merohedral twin, with a 33% twin component.

Original language	English
Pages (from-to)	o1864
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	8
DOIs	https://doi.org/10.1107/S1600536809026683
Publication status	Published - 1 Jan 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{4c185f5416fb4d6687e19b6069d9ce8b,

title = "2,3-Bis(3-fluoro-phen-yl)tetra-zolium-5-thiol-ate",

abstract = "The zwitterionic title compound, C13H8F 2N4S, is situated on a twofold rotation axis running along the C - S [1.691 (2) {\AA}] single bond. The phenyl-ene ring is twisted out of the tetra-zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) {\AA}] between the centroids of the phenyl-ene and tetra-zolium rings of neighbouring mol-ecules suggest π-π inter-actions. The crystal under investigation was a non-merohedral twin, with a 33\% twin component.",

author = "\{von Eschwege\}, \{Karel G.\} and Alfred Muller",

year = "2009",

month = jan,

day = "1",

doi = "10.1107/S1600536809026683",

language = "English",

volume = "65",

pages = "o1864",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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TY - JOUR

T1 - 2,3-Bis(3-fluoro-phen-yl)tetra-zolium-5-thiol-ate

AU - von Eschwege, Karel G.

AU - Muller, Alfred

PY - 2009/1/1

Y1 - 2009/1/1

N2 - The zwitterionic title compound, C13H8F 2N4S, is situated on a twofold rotation axis running along the C - S [1.691 (2) Å] single bond. The phenyl-ene ring is twisted out of the tetra-zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) Å] between the centroids of the phenyl-ene and tetra-zolium rings of neighbouring mol-ecules suggest π-π inter-actions. The crystal under investigation was a non-merohedral twin, with a 33% twin component.

AB - The zwitterionic title compound, C13H8F 2N4S, is situated on a twofold rotation axis running along the C - S [1.691 (2) Å] single bond. The phenyl-ene ring is twisted out of the tetra-zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) Å] between the centroids of the phenyl-ene and tetra-zolium rings of neighbouring mol-ecules suggest π-π inter-actions. The crystal under investigation was a non-merohedral twin, with a 33% twin component.

UR - https://www.scopus.com/pages/publications/68749117599

U2 - 10.1107/S1600536809026683

DO - 10.1107/S1600536809026683

M3 - Article

AN - SCOPUS:68749117599

SN - 1600-5368

VL - 65

SP - o1864

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

2,3-Bis(3-fluoro-phen-yl)tetra-zolium-5-thiol-ate

Abstract

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