2,3-Bis(2-methoxyphenyl)tetrazolium-5-thiolateacetonedichloromethane (1/0.4/0.1)

Karel G. Von Eschwege; Alfred Muller

doi:10.1107/S1600536808039731

2,3-Bis(2-methoxyphenyl)tetrazolium-5-thiolateacetonedichloromethane (1/0.4/0.1)

Karel G. Von Eschwege, Alfred Muller

Chemical Sciences

University of The Free State

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, C15H14N4O2S·0.4C3H6O·0.1CH2Cl2, two benzene rings in the ortho-meth-oxy dehydro-dithizone (omd) mol-ecule are twisted out of the tetra-zole plane with the meth-oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) Å between the centroids of benzene rings from two neighbouring omd mol-ecules indicate π-π stacking inter-actions.

Original language	English
Pages (from-to)	o2
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	1
DOIs	https://doi.org/10.1107/S1600536808039731
Publication status	Published - 2008

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "2,3-Bis(2-methoxyphenyl)tetrazolium-5-thiolateacetonedichloromethane (1/0.4/0.1)",

abstract = "In the title compound, C15H14N4O2S·0.4C3H6O·0.1CH2Cl2, two benzene rings in the ortho-meth-oxy dehydro-dithizone (omd) mol-ecule are twisted out of the tetra-zole plane with the meth-oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) {\AA} between the centroids of benzene rings from two neighbouring omd mol-ecules indicate π-π stacking inter-actions.",

author = "\{Von Eschwege\}, \{Karel G.\} and Alfred Muller",

year = "2008",

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T1 - 2,3-Bis(2-methoxyphenyl)tetrazolium-5-thiolateacetonedichloromethane (1/0.4/0.1)

AU - Von Eschwege, Karel G.

AU - Muller, Alfred

PY - 2008

Y1 - 2008

N2 - In the title compound, C15H14N4O2S·0.4C3H6O·0.1CH2Cl2, two benzene rings in the ortho-meth-oxy dehydro-dithizone (omd) mol-ecule are twisted out of the tetra-zole plane with the meth-oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) Å between the centroids of benzene rings from two neighbouring omd mol-ecules indicate π-π stacking inter-actions.

AB - In the title compound, C15H14N4O2S·0.4C3H6O·0.1CH2Cl2, two benzene rings in the ortho-meth-oxy dehydro-dithizone (omd) mol-ecule are twisted out of the tetra-zole plane with the meth-oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) Å between the centroids of benzene rings from two neighbouring omd mol-ecules indicate π-π stacking inter-actions.

UR - https://www.scopus.com/pages/publications/58149465725

U2 - 10.1107/S1600536808039731

DO - 10.1107/S1600536808039731

M3 - Article

AN - SCOPUS:58149465725

SN - 1600-5368

VL - 65

SP - o2

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

2,3-Bis(2-methoxyphenyl)tetrazolium-5-thiolateacetonedichloromethane (1/0.4/0.1)

Abstract

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