[2-(Anilinomethyl)phenyl]diphenyl phosphine and {2-[(N-methylanilino)- methyl]phenyl}diphenylphosphine

Marié Pretorius; D. Bradley G. Williams; Andreas Roodt; Alfred Muller

doi:10.1107/S0108270104007693

[2-(Anilinomethyl)phenyl]diphenyl phosphine and {2-[(N-methylanilino)- methyl]phenyl}diphenylphosphine

Marié Pretorius, D. Bradley G. Williams, Andreas Roodt, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The properties of two isomers C₂₅H₂₂NP and C ₂₆H₂₄NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.

Original language	English
Pages (from-to)	o384-o386
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	6
DOIs	https://doi.org/10.1107/S0108270104007693
Publication status	Published - Jun 2004

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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title = "[2-(Anilinomethyl)phenyl]diphenyl phosphine and \{2-[(N-methylanilino)- methyl]phenyl\}diphenylphosphine",

abstract = "The properties of two isomers C25H22NP and C 26H24NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.",

author = "Mari{\'e} Pretorius and Williams, \{D. Bradley G.\} and Andreas Roodt and Alfred Muller",

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doi = "10.1107/S0108270104007693",

language = "English",

volume = "60",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

number = "6",

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T1 - [2-(Anilinomethyl)phenyl]diphenyl phosphine and {2-[(N-methylanilino)- methyl]phenyl}diphenylphosphine

AU - Pretorius, Marié

AU - Williams, D. Bradley G.

AU - Roodt, Andreas

AU - Muller, Alfred

PY - 2004/6

Y1 - 2004/6

N2 - The properties of two isomers C25H22NP and C 26H24NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.

AB - The properties of two isomers C25H22NP and C 26H24NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.

UR - https://www.scopus.com/pages/publications/3142601413

U2 - 10.1107/S0108270104007693

DO - 10.1107/S0108270104007693

M3 - Article

AN - SCOPUS:3142601413

SN - 0108-2701

VL - 60

SP - o384-o386

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

[2-(Anilinomethyl)phenyl]diphenyl phosphine and {2-[(N-methylanilino)- methyl]phenyl}diphenylphosphine

Abstract

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