TY - JOUR
T1 - [2-(Anilinomethyl)phenyl]diphenyl phosphine and {2-[(N-methylanilino)- methyl]phenyl}diphenylphosphine
AU - Pretorius, Marié
AU - Williams, D. Bradley G.
AU - Roodt, Andreas
AU - Muller, Alfred
PY - 2004/6
Y1 - 2004/6
N2 - The properties of two isomers C25H22NP and C 26H24NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.
AB - The properties of two isomers C25H22NP and C 26H24NP along with Tolman angles were compared. It was observed that the two compounds were isomorphous, having individual molecules in the centrosymmetric space group C2/c (Z=8). It was also observed that the calculation of the Tolman cone angle was helpful in determining ligand steric behaviour at a metal centre. The results show that the Tolman angle was important for monodentate or monocoordinated ligands.
UR - http://www.scopus.com/inward/record.url?scp=3142601413&partnerID=8YFLogxK
U2 - 10.1107/S0108270104007693
DO - 10.1107/S0108270104007693
M3 - Article
AN - SCOPUS:3142601413
SN - 0108-2701
VL - 60
SP - o384-o386
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 6
ER -