[2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)

John Bacsa; Richard M. Moutloali; James Darkwa

doi:10.1107/S0108270101020182

[2, 6-Bis(isopropylthiomethyl)phenyl-κ³S, C¹, S ′]bromopalladium(II)

John Bacsa, Richard M. Moutloali, James Darkwa

University of Cape Town

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystal structure of the compound [PdBr(C₁₄H₂₁S₂)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

Original language	English
Pages (from-to)	m109-m110
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	2
DOIs	https://doi.org/10.1107/S0108270101020182
Publication status	Published - Feb 2002
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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10.1107/S0108270101020182

Cite this

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title = "[2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)",

abstract = "The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.",

author = "John Bacsa and Moutloali, \{Richard M.\} and James Darkwa",

year = "2002",

month = feb,

doi = "10.1107/S0108270101020182",

language = "English",

volume = "58",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

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T1 - [2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)

AU - Bacsa, John

AU - Moutloali, Richard M.

AU - Darkwa, James

PY - 2002/2

Y1 - 2002/2

N2 - The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

AB - The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

UR - https://www.scopus.com/pages/publications/0036486898

U2 - 10.1107/S0108270101020182

DO - 10.1107/S0108270101020182

M3 - Article

AN - SCOPUS:0036486898

SN - 0108-2701

VL - 58

SP - m109-m110

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

[2, 6-Bis(isopropylthiomethyl)phenyl-κ³S, C¹, S ′]bromopalladium(II)

Abstract

ASJC Scopus subject areas

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