[2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)

John Bacsa; Richard M. Moutloali; James Darkwa

doi:10.1107/S0108270101020182

[2, 6-Bis(isopropylthiomethyl)phenyl-κ³S, C¹, S ′]bromopalladium(II)

John Bacsa, Richard M. Moutloali, James Darkwa

University of Cape Town

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystal structure of the compound [PdBr(C₁₄H₂₁S₂)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

Original language	English
Pages (from-to)	m109-m110
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	2
DOIs	https://doi.org/10.1107/S0108270101020182
Publication status	Published - Feb 2002
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

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10.1107/S0108270101020182

Cite this

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title = "[2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)",

abstract = "The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.",

author = "John Bacsa and Moutloali, {Richard M.} and James Darkwa",

year = "2002",

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T1 - [2, 6-Bis(isopropylthiomethyl)phenyl-κ3S, C1, S ′]bromopalladium(II)

AU - Bacsa, John

AU - Moutloali, Richard M.

AU - Darkwa, James

PY - 2002/2

Y1 - 2002/2

N2 - The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

AB - The crystal structure of the compound [PdBr(C14H21S2)] exhibited square-planar geometry at the Pd center. Three atoms of the square plane were provided by the rigid thiopincer ligand. The thiopincer ligand complexes were formed by the cyclometallation of 1, 3-bis(disubstituted thiomethyl)benzene.

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U2 - 10.1107/S0108270101020182

DO - 10.1107/S0108270101020182

M3 - Article

AN - SCOPUS:0036486898

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VL - 58

SP - m109-m110

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

[2, 6-Bis(isopropylthiomethyl)phenyl-κ³S, C¹, S ′]bromopalladium(II)

Abstract

ASJC Scopus subject areas

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