(1R*,5S*,6S*,7R*)-6,7-Dihydroxy-6-hydroxymethyl-2- oxabicyclo[3.2.0]-heptan-3-one

Judy Caddy; D. Bradley G. Williams; Andreas Roodt; Alfred Muller

doi:10.1107/S1600536803014557

(1R,5S,6S,7R)-6,7-Dihydroxy-6-hydroxymethyl-2- oxabicyclo[3.2.0]-heptan-3-one

Judy Caddy, D. Bradley G. Williams, Andreas Roodt, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The crystal structure analysis of the title compound, C₇H ₁₀O₅, shows that a four-five lactonization instead of a four-six self condensation took place during the reaction sequence. The structure is stabilized by strong hydrogen-bonding interactions that serve to form a layer structure. The absolute configuration was assigned based on the chemical synthesis from a starting material of known chirality.

Original language	English
Pages (from-to)	o1095-o1097
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	8
DOIs	https://doi.org/10.1107/S1600536803014557
Publication status	Published - Aug 2003

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(1R*,5S*,6S*,7R*)-6,7-Dihydroxy-6-hydroxymethyl-2- oxabicyclo[3.2.0]-heptan-3-one",

abstract = "The crystal structure analysis of the title compound, C7H 10O5, shows that a four-five lactonization instead of a four-six self condensation took place during the reaction sequence. The structure is stabilized by strong hydrogen-bonding interactions that serve to form a layer structure. The absolute configuration was assigned based on the chemical synthesis from a starting material of known chirality.",

author = "Judy Caddy and Williams, {D. Bradley G.} and Andreas Roodt and Alfred Muller",

year = "2003",

month = aug,

doi = "10.1107/S1600536803014557",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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AU - Caddy, Judy

AU - Williams, D. Bradley G.

AU - Roodt, Andreas

AU - Muller, Alfred

PY - 2003/8

Y1 - 2003/8

N2 - The crystal structure analysis of the title compound, C7H 10O5, shows that a four-five lactonization instead of a four-six self condensation took place during the reaction sequence. The structure is stabilized by strong hydrogen-bonding interactions that serve to form a layer structure. The absolute configuration was assigned based on the chemical synthesis from a starting material of known chirality.

AB - The crystal structure analysis of the title compound, C7H 10O5, shows that a four-five lactonization instead of a four-six self condensation took place during the reaction sequence. The structure is stabilized by strong hydrogen-bonding interactions that serve to form a layer structure. The absolute configuration was assigned based on the chemical synthesis from a starting material of known chirality.

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DO - 10.1107/S1600536803014557

M3 - Article

AN - SCOPUS:4544228085

SN - 1600-5368

VL - 59

SP - o1095-o1097

JO - Acta Crystallographica Section E: Structure Reports Online

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ER -

(1R,5S,6S,7R)-6,7-Dihydroxy-6-hydroxymethyl-2- oxabicyclo[3.2.0]-heptan-3-one

Abstract

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