[1,5-Bis(2-methoxyphenyl)thiocarbazonato-κ2N 5,S]phenylmercury(II)

Karel G. von Eschwege; Fabian Muller; Alfred Muller

doi:10.1107/S1600536811049099

[1,5-Bis(2-methoxyphenyl)thiocarbazonato-κ²N ⁵,S]phenylmercury(II)

Karel G. von Eschwege, Fabian Muller, Alfred Muller

Chemical Sciences

University of The Free State

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The title compound, [Hg(C₆H₅)(C₁₅H ₁₅N₄O₂S)], shows the metalphenyl moiety coordinated out of plane with the thiocarbazonate ligand by 43.84 (6)°. Important geometrical parameters include Hg - S = 2.3653 (10) Å, Hg - C = 2.058 (4) Å and S - Hg - C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg - N = 2.725 (3) Å]. S⋯Hg interactions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.

Original language	English
Pages (from-to)	m1804
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811049099
Publication status	Published - Dec 2011

Keywords

R factor = 0.030
T = 299 K
data-to-parameter ratio = 19.3
mean σ(C-C) = 0.007 Å
single-crystal X-ray study
wR factor = 0.076

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811049099

Cite this

@article{2126dd523b3147f0b251ea60058484c3,

title = "[1,5-Bis(2-methoxyphenyl)thiocarbazonato-κ2N 5,S]phenylmercury(II)",

abstract = "The title compound, [Hg(C6H5)(C15H 15N4O2S)], shows the metalphenyl moiety coordinated out of plane with the thiocarbazonate ligand by 43.84 (6)°. Important geometrical parameters include Hg - S = 2.3653 (10) {\AA}, Hg - C = 2.058 (4) {\AA} and S - Hg - C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg - N = 2.725 (3) {\AA}]. S⋯Hg interactions[3.2928 (10) {\AA}] form chains along [001], stabilizing the crystal structure.",

keywords = "R factor = 0.030, T = 299 K, data-to-parameter ratio = 19.3, mean σ(C-C) = 0.007 {\AA}, single-crystal X-ray study, wR factor = 0.076",

author = "{von Eschwege}, {Karel G.} and Fabian Muller and Alfred Muller",

year = "2011",

month = dec,

doi = "10.1107/S1600536811049099",

language = "English",

volume = "67",

pages = "m1804",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "12",

}

TY - JOUR

T1 - [1,5-Bis(2-methoxyphenyl)thiocarbazonato-κ2N 5,S]phenylmercury(II)

AU - von Eschwege, Karel G.

AU - Muller, Fabian

AU - Muller, Alfred

PY - 2011/12

Y1 - 2011/12

N2 - The title compound, [Hg(C6H5)(C15H 15N4O2S)], shows the metalphenyl moiety coordinated out of plane with the thiocarbazonate ligand by 43.84 (6)°. Important geometrical parameters include Hg - S = 2.3653 (10) Å, Hg - C = 2.058 (4) Å and S - Hg - C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg - N = 2.725 (3) Å]. S⋯Hg interactions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.

AB - The title compound, [Hg(C6H5)(C15H 15N4O2S)], shows the metalphenyl moiety coordinated out of plane with the thiocarbazonate ligand by 43.84 (6)°. Important geometrical parameters include Hg - S = 2.3653 (10) Å, Hg - C = 2.058 (4) Å and S - Hg - C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg - N = 2.725 (3) Å]. S⋯Hg interactions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.

KW - R factor = 0.030

KW - T = 299 K

KW - data-to-parameter ratio = 19.3

KW - mean σ(C-C) = 0.007 Å

KW - single-crystal X-ray study

KW - wR factor = 0.076

UR - http://www.scopus.com/inward/record.url?scp=83155178469&partnerID=8YFLogxK

U2 - 10.1107/S1600536811049099

DO - 10.1107/S1600536811049099

M3 - Article

AN - SCOPUS:83155178469

SN - 1600-5368

VL - 67

SP - m1804

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -