1,5-Anhydro-3,6-di-O-benzyl-2-deoxy-1,2-C-dichloromethylene-D-glycero-D- gulo-hexitol

Henok H. Kinfe; Blessing A. Aderibigbe; Alfred Muller

doi:10.1107/S1600536811040815

1,5-Anhydro-3,6-di-O-benzyl-2-deoxy-1,2-C-dichloromethylene-D-glycero-D- gulo-hexitol

Henok H. Kinfe
, Blessing A. Aderibigbe
, Alfred Muller

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C₂₁H₂₂Cl₂O ₄, the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O - H⋯O hydrogen bonding results in infinite chains of molecules along [100]. The structure is further consolidated by weak C - H⋯O, C - H⋯Cl and C - H⋯π interactions. The absolute structure was determined.

Original language	English
Pages (from-to)	o2888
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	11
DOIs	https://doi.org/10.1107/S1600536811040815
Publication status	Published - Nov 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536811040815

Cite this

@article{8cb2fb9bec974db5beda784c4524986a,

title = "1,5-Anhydro-3,6-di-O-benzyl-2-deoxy-1,2-C-dichloromethylene-D-glycero-D- gulo-hexitol",

abstract = "In the title compound, C21H22Cl2O 4, the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O - H⋯O hydrogen bonding results in infinite chains of molecules along [100]. The structure is further consolidated by weak C - H⋯O, C - H⋯Cl and C - H⋯π interactions. The absolute structure was determined.",

author = "Kinfe, \{Henok H.\} and Aderibigbe, \{Blessing A.\} and Alfred Muller",

year = "2011",

month = nov,

doi = "10.1107/S1600536811040815",

language = "English",

volume = "67",

pages = "o2888",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - 1,5-Anhydro-3,6-di-O-benzyl-2-deoxy-1,2-C-dichloromethylene-D-glycero-D- gulo-hexitol

AU - Kinfe, Henok H.

AU - Aderibigbe, Blessing A.

AU - Muller, Alfred

PY - 2011/11

Y1 - 2011/11

N2 - In the title compound, C21H22Cl2O 4, the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O - H⋯O hydrogen bonding results in infinite chains of molecules along [100]. The structure is further consolidated by weak C - H⋯O, C - H⋯Cl and C - H⋯π interactions. The absolute structure was determined.

AB - In the title compound, C21H22Cl2O 4, the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O - H⋯O hydrogen bonding results in infinite chains of molecules along [100]. The structure is further consolidated by weak C - H⋯O, C - H⋯Cl and C - H⋯π interactions. The absolute structure was determined.

UR - https://www.scopus.com/pages/publications/84455211481

U2 - 10.1107/S1600536811040815

DO - 10.1107/S1600536811040815

M3 - Article

AN - SCOPUS:84455211481

SN - 1600-5368

VL - 67

SP - o2888

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

1,5-Anhydro-3,6-di-O-benzyl-2-deoxy-1,2-C-dichloromethylene-D-glycero-D- gulo-hexitol

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this