1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene) methanamine

Haleden Chiririwa; John R. Moss; Denver Hendricks; Reinout Meijboom

doi:10.1107/S1600536812040809

1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene) methanamine

Haleden Chiririwa, John R. Moss, Denver Hendricks, Reinout Meijboom

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound C₁₈H₁6N₂S₂, crystallizes with two independent half-molecules in the asymmetric unit, in one of which the thiophene rings are disordered in a 0.67:0.33 ratio. Each independent molecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.

Original language	English
Pages (from-to)	o3137
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	11
DOIs	https://doi.org/10.1107/S1600536812040809
Publication status	Published - Nov 2012

Keywords

R factor = 0.045
T = 173 K
data-to-parameter ratio = 15.9
disorder in main residue
mean ̄(C-C) = 0.004 Å
single-crystal X-ray study
wR factor = 0.125

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene) methanamine",

abstract = "The title compound C18H16N2S2, crystallizes with two independent half-molecules in the asymmetric unit, in one of which the thiophene rings are disordered in a 0.67:0.33 ratio. Each independent molecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.",

keywords = "R factor = 0.045, T = 173 K, data-to-parameter ratio = 15.9, disorder in main residue, mean{\= }(C-C) = 0.004 {\AA}, single-crystal X-ray study, wR factor = 0.125",

author = "Haleden Chiririwa and Moss, {John R.} and Denver Hendricks and Reinout Meijboom",

year = "2012",

month = nov,

doi = "10.1107/S1600536812040809",

language = "English",

volume = "68",

pages = "o3137",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

}

TY - JOUR

T1 - 1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene) methanamine

AU - Chiririwa, Haleden

AU - Moss, John R.

AU - Hendricks, Denver

AU - Meijboom, Reinout

PY - 2012/11

Y1 - 2012/11

N2 - The title compound C18H16N2S2, crystallizes with two independent half-molecules in the asymmetric unit, in one of which the thiophene rings are disordered in a 0.67:0.33 ratio. Each independent molecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.

AB - The title compound C18H16N2S2, crystallizes with two independent half-molecules in the asymmetric unit, in one of which the thiophene rings are disordered in a 0.67:0.33 ratio. Each independent molecule lies across a crystallographic centre of symmetry. The dihedral angle between central (half) benzene ring and the thiophene ring is 11.82°.

KW - R factor = 0.045

KW - T = 173 K

KW - data-to-parameter ratio = 15.9

KW - disorder in main residue

KW - mean ̄(C-C) = 0.004 Å

KW - single-crystal X-ray study

KW - wR factor = 0.125

UR - http://www.scopus.com/inward/record.url?scp=84870909209&partnerID=8YFLogxK

U2 - 10.1107/S1600536812040809

DO - 10.1107/S1600536812040809

M3 - Article

AN - SCOPUS:84870909209

SN - 1600-5368

VL - 68

SP - o3137

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

1-(Thiophen-2-yl)-N-(4-{(E)-[(thiophen-2-yl)methyl]iminomethyl}benzylidene) methanamine

Abstract

Keywords

ASJC Scopus subject areas

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