TY - JOUR
T1 - {1-[1-(3-Carboxypropanamido)ethyl]-1′,2-bis-(diphenylphosphino) ferroceneκ2 P,P′}dichloridoplatinum(II) dichloro-methane 1.25-solvate
AU - Spencer, Lara C.
AU - Bjelosevic, Haris
AU - Darkwa, James
AU - Elmroth, Sofi K.C.
AU - Persson, Tina
PY - 2008
Y1 - 2008
N2 - The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]·1. 25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O - H⋯O bonds resulting in R 2 2(8) rings. A weak intra-molecular N - H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
AB - The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]·1. 25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O - H⋯O bonds resulting in R 2 2(8) rings. A weak intra-molecular N - H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
UR - http://www.scopus.com/inward/record.url?scp=37849004549&partnerID=8YFLogxK
U2 - 10.1107/S1600536807065105
DO - 10.1107/S1600536807065105
M3 - Article
AN - SCOPUS:37849004549
SN - 1600-5368
VL - 64
SP - m164-m165
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 1
ER -