(μ-Piperazine-1,4-dicarbodithioato-κ4 S1,S 1′:S4,S 4′)bis[bis- (triphenylphosphane-κP)gold(I)] chloroform disolvate

Ilia A. Guzei; Lara C. Spencer; Stacy Lillywhite; James Darkwa

doi:10.1107/S1600536811044229

(μ-Piperazine-1,4-dicarbodithioato-κ⁴ S¹,S ^1′:S⁴,S ^4′)bis[bis- (triphenylphosphane-κP)gold(I)] chloroform disolvate

Ilia A. Guzei, Lara C. Spencer, Stacy Lillywhite, James Darkwa

Chemical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In the title compound, [Au₂(C₆H₈N ₂S₄)(C₁₈H₁₅P)₄] ·2CHCl₃, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S - Au - S bite angle.

Original language	English
Pages (from-to)	m1629-m1630
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	11
DOIs	https://doi.org/10.1107/S1600536811044229
Publication status	Published - Nov 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(μ-Piperazine-1,4-dicarbodithioato-κ4 S1,S 1′:S4,S 4′)bis[bis- (triphenylphosphane-κP)gold(I)] chloroform disolvate",

abstract = "In the title compound, [Au2(C6H8N 2S4)(C18H15P)4] ·2CHCl3, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S - Au - S bite angle.",

author = "Guzei, {Ilia A.} and Spencer, {Lara C.} and Stacy Lillywhite and James Darkwa",

year = "2011",

month = nov,

doi = "10.1107/S1600536811044229",

language = "English",

volume = "67",

pages = "m1629--m1630",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

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TY - JOUR

T1 - (μ-Piperazine-1,4-dicarbodithioato-κ4 S1,S 1′:S4,S 4′)bis[bis- (triphenylphosphane-κP)gold(I)] chloroform disolvate

AU - Guzei, Ilia A.

AU - Spencer, Lara C.

AU - Lillywhite, Stacy

AU - Darkwa, James

PY - 2011/11

Y1 - 2011/11

N2 - In the title compound, [Au2(C6H8N 2S4)(C18H15P)4] ·2CHCl3, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S - Au - S bite angle.

AB - In the title compound, [Au2(C6H8N 2S4)(C18H15P)4] ·2CHCl3, the digold complex resides on a crystallographic inversion center and co-crystallizes with two molecules of chloro-form solvent. The piperazine-1,4-dicarbodithio-ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra-hedral punctuated by a very acute S - Au - S bite angle.

UR - http://www.scopus.com/inward/record.url?scp=84455183078&partnerID=8YFLogxK

U2 - 10.1107/S1600536811044229

DO - 10.1107/S1600536811044229

M3 - Article

AN - SCOPUS:84455183078

SN - 1600-5368

VL - 67

SP - m1629-m1630

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

(μ-Piperazine-1,4-dicarbodithioato-κ⁴ S¹,S ^1′:S⁴,S ^4′)bis[bis- (triphenylphosphane-κP)gold(I)] chloroform disolvate

Abstract

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