μ-2,2′-Biphenolato-k2 O:O′-μ-oxido-k 2 O:O-bis-[bis-(hexa-fluoro-acetyl-acetonato-k2 O,O′)titanium(IV)]

Annemarie Kuhn, Alfred Muller, Jeanet Conradie

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)


The coordination of [Ti(hfaa)2Cl2] (hfaa = hexa-fluoro-acetyl-acetonate) with the hydroxyl-containing bidentate ligand 2,2′-biphenol yielded the title compound, [{Ti(hfaa)2}2(μ-2,2′-biphenolato)(μ-oxo)] or [Ti2(C5HF6O2)4(C12H8O2)O]. The molecule has crystallographic twofold rotation symmetry. The biphenolate ligand bridges the two Ti atoms.

Original languageEnglish
Article numberhg2178
Pages (from-to)m664-m666
JournalActa Crystallographica Section E: Structure Reports Online
Issue number3
Publication statusPublished - 28 Feb 2007
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


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