{μ-2-[1-(N,N-dimethylamino)ethyl]ferrocene-1,1′- diylbis(diphenylphosphine)-k2P:P′}bis[thiocyanatogold(I)]

Zolisa A. Sam; Sofi K.C. Elmroth; Andreas Roodt; Alfred J. Muller

doi:10.1107/S1600536806024354

{μ-2-[1-(N,N-dimethylamino)ethyl]ferrocene-1,1′- diylbis(diphenylphosphine)-k²P:P′}bis[thiocyanatogold(I)]

Zolisa A. Sam, Sofi K.C. Elmroth, Andreas Roodt, Alfred J. Muller

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Au₂Fe(C₃₈H₃₇NP ₂)(SCN)₂], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl-phosphine ligand. Selected geometrical parameters for the compound are Au - P = 2.265 (2) and 2.260 (3) Å, Au - S = 2.327(3) and 2.313 (3) Å, and P -Au - S = 175.61 (9) and 176.86 (9)°.

Original language	English
Pages (from-to)	m1699-m1701
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	7
DOIs	https://doi.org/10.1107/S1600536806024354
Publication status	Published - Jul 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{d908e4dd9054445ebf2184cd3542d53e,

title = "{μ-2-[1-(N,N-dimethylamino)ethyl]ferrocene-1,1′- diylbis(diphenylphosphine)-k2P:P′}bis[thiocyanatogold(I)]",

abstract = "The title compound, [Au2Fe(C38H37NP 2)(SCN)2], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl-phosphine ligand. Selected geometrical parameters for the compound are Au - P = 2.265 (2) and 2.260 (3) {\AA}, Au - S = 2.327(3) and 2.313 (3) {\AA}, and P -Au - S = 175.61 (9) and 176.86 (9)°.",

author = "Sam, {Zolisa A.} and Elmroth, {Sofi K.C.} and Andreas Roodt and Muller, {Alfred J.}",

year = "2006",

month = jul,

doi = "10.1107/S1600536806024354",

language = "English",

volume = "62",

pages = "m1699--m1701",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "7",

}

TY - JOUR

T1 - {μ-2-[1-(N,N-dimethylamino)ethyl]ferrocene-1,1′- diylbis(diphenylphosphine)-k2P:P′}bis[thiocyanatogold(I)]

AU - Sam, Zolisa A.

AU - Elmroth, Sofi K.C.

AU - Roodt, Andreas

AU - Muller, Alfred J.

PY - 2006/7

Y1 - 2006/7

N2 - The title compound, [Au2Fe(C38H37NP 2)(SCN)2], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl-phosphine ligand. Selected geometrical parameters for the compound are Au - P = 2.265 (2) and 2.260 (3) Å, Au - S = 2.327(3) and 2.313 (3) Å, and P -Au - S = 175.61 (9) and 176.86 (9)°.

AB - The title compound, [Au2Fe(C38H37NP 2)(SCN)2], is a dinuclear gold(I) complex containing an unsymmetrical bidentate ferrocenyl-phosphine ligand. Selected geometrical parameters for the compound are Au - P = 2.265 (2) and 2.260 (3) Å, Au - S = 2.327(3) and 2.313 (3) Å, and P -Au - S = 175.61 (9) and 176.86 (9)°.

UR - http://www.scopus.com/inward/record.url?scp=33746010568&partnerID=8YFLogxK

U2 - 10.1107/S1600536806024354

DO - 10.1107/S1600536806024354

M3 - Article

AN - SCOPUS:33746010568

SN - 1600-5368

VL - 62

SP - m1699-m1701

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

{μ-2-[1-(N,N-dimethylamino)ethyl]ferrocene-1,1′- diylbis(diphenylphosphine)-k²P:P′}bis[thiocyanatogold(I)]

Abstract

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