{μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-k2 N 2:N 2′}di -μ-chloridobis-[chloridopalladium(II)] toluene solvate

Bernard Omondi; Asheena Budhai; James Darkwa

doi:10.1107/S1600536809010629

{μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-k² N ²:N ^2′}di -μ-chloridobis-[chloridopalladium(II)] toluene solvate

Bernard Omondi, Asheena Budhai, James Darkwa

Chemical Sciences

University of Johannesburg

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title complex, [Pd₂Cl₄(C₁₈H ₂₂N₄)]·C₇H₈, each of the two four-coordinated Pd^II atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C - H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.

Original language	English
Pages (from-to)	m446
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	4
DOIs	https://doi.org/10.1107/S1600536809010629
Publication status	Published - 2009

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "{μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-k2 N 2:N 2′}di -μ-chloridobis-[chloridopalladium(II)] toluene solvate",

abstract = "In the title complex, [Pd2Cl4(C18H 22N4)]·C7H8, each of the two four-coordinated PdII atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C - H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.",

author = "Bernard Omondi and Asheena Budhai and James Darkwa",

year = "2009",

doi = "10.1107/S1600536809010629",

language = "English",

volume = "65",

pages = "m446",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "4",

}

TY - JOUR

T1 - {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-k2 N 2:N 2′}di -μ-chloridobis-[chloridopalladium(II)] toluene solvate

AU - Omondi, Bernard

AU - Budhai, Asheena

AU - Darkwa, James

PY - 2009

Y1 - 2009

N2 - In the title complex, [Pd2Cl4(C18H 22N4)]·C7H8, each of the two four-coordinated PdII atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C - H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.

AB - In the title complex, [Pd2Cl4(C18H 22N4)]·C7H8, each of the two four-coordinated PdII atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C - H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.

UR - http://www.scopus.com/inward/record.url?scp=64149095763&partnerID=8YFLogxK

U2 - 10.1107/S1600536809010629

DO - 10.1107/S1600536809010629

M3 - Article

AN - SCOPUS:64149095763

SN - 1600-5368

VL - 65

SP - m446

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

{μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-k² N ²:N ^2′}di -μ-chloridobis-[chloridopalladium(II)] toluene solvate

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